ZrCl4-promoted halogen migration during an electrophilic amination of halogenated phenols

被引：39

作者：

Bombek, S

Lenarsic, R

Kocevar, M

Saint-Jalmes, L

Desmurs, JR

Polanc, S

机构：

[1] Univ Ljubljana, Fac Chem & Chem Technol, SI-1000 Ljubljana, Slovenia

[2] KRKA DD, SI-8000 Novo Mesto, Slovenia

[3] Rhodia Ctr Rech Lyon, F-69192 St Fons, France

[4] Rhodia, Pharmaceut Ingredients Etoile Part Dieu, F-69457 Lyon 06, France

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 14期

关键词：

D O I：

10.1039/b203622c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An electrophilic amination of halogenated phenols with diisopropyl diazenedicarboxylate in the presence of ZrCl4 as a Lewis acid, accompanied by a halogen migration, was demonstrated for the first time; the fluorine, chlorine, bromine, or iodine atom migrated during the amination process under mild reaction conditions.

引用

页码：1494 / 1495

页数：2

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[11] BASE-CATALYZED HALOGEN DANCE, AND OTHER REACTIONS OF ARYL HALIDES [J].