Low-temperature synthesis of nanocrystalline ZrP via co-reduction of ZrCl4 and PCl3

被引：7

作者：

Chen, LY ^{[1
]}

Huang, MX ^{[1
]}

Gu, YL ^{[1
]}

Shi, L ^{[1
]}

Yang, ZH ^{[1
]}

Qian, YT ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Chem & Struct Res Lab, Anhua 230026, Peoples R China

来源：

MATERIALS LETTERS | 2004年 / 58卷 / 26期

关键词：

X-ray diffraction; dendrites; phosphides;

D O I：

10.1016/j.matlet.2004.06.033

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Zirconium phosphide (ZrP) has been synthesized via a sodium co reduction of ZrCl4 and PCl3 at 350 degreesC. The X-ray powder diffraction (XRD) pattern can be indexed as cubic ZrP with the lattice constant a = 5.25 Angstrom. The transmission electron microscopy (TEM) image indicates the product has dendritic morphology and hexagonal flakes. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：3337 / 3339

页数：3

共 11 条

[1]

BLITZ W, 1938, Z ANORG CHEM, V238, P395, DOI DOI 10.1002/ZAAC.19382380408

[2] CVD growth and morphology of transition-metal phosphides [J].

Fujii, M ;

Iwanaga, H ;

Motojima, S .

JOURNAL OF CRYSTAL GROWTH, 1996, 166 (1-4) :99-103

[3] STABILITY AND VAPORIZATION BEHAVIOUR OF GROUP IV-VI TRANSITION METAL MONOPHOSPHIDES [J].

GINGERICH, KA .

NATURE, 1963, 200 (490) :877-&

[4] Self-propagating metathesis routes to metastable group 4 phosphides [J].

Jarvis, RF ;

Jacubinas, RM ;

Kaner, RB .

INORGANIC CHEMISTRY, 2000, 39 (15) :3243-3246

[5] STUDIES OF CRYSTAL STRUCTURES AND PHASE RELATIONSHIPS IN TI-P SYSTEM [J].

LUNDSTRO.T ;

SNELL, PO .

ACTA CHEMICA SCANDINAVICA, 1967, 21 (05) :1343-&

[6] SYNTHESIS OF TRANSITION-METAL PHOSPHIDES FROM THEIR OXIDES USING THE CHEMICAL-TRANSPORT (CVT) METHOD [J].

MARTIN, J ;

GRUEHN, R .

SOLID STATE IONICS, 1990, 43 :19-22

[7] CRYSTAL-GROWTH AND SOME PROPERTIES OF TITANIUM MONOPHOSPHIDE [J].

MOTOJIMA, S ;

WAKAMATSU, T ;

TAKAHASHI, Y ;

SUGIYAMA, K .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1976, 123 (02) :290-295

[8] THE PREPARATION AND PROPERTIES OF SOME TRANSITION PHOSPHIDES [J].

RIPLEY, RL .

JOURNAL OF THE LESS-COMMON METALS, 1962, 4 (06) :496-503

[9]

SHONBERG N, 1954, ACTA CHEM SCAND, V8, P226

[10] Articles on the systematic study of correlation 84 ziconium phosphide. [J].

Strotzer, EF ;

Biltz, W ;

Meisel, K .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1938, 239 (02) :216-224

← 1 2 →