Solution-Grown, Macroscopic Organic Single Crystals Exhibiting Three-Dimensional Anisotropic Charge-Transport Properties

被引:43
作者
Fraboni, Beatrice [1 ,2 ]
Femoni, Cristina [3 ]
Mencarelli, Ivan [4 ]
Setti, Leonardo [4 ]
Di Pietro, Riccardo [2 ]
Cavallini, Anna [2 ]
Fraleoni-Morgera, Alessandro
机构
[1] Sincrotrone Trieste, I-34012 Trieste, Italy
[2] Univ Bologna, Dept Phys, I-40127 Bologna, Italy
[3] Univ Bologna, Dept Phys & Inorgan Chem, I-40136 Bologna, Italy
[4] Univ Bologna, Dept Ind & Mat Chem, I-40136 Bologna, Italy
关键词
FIELD-EFFECT TRANSISTORS; MOBILITY; IMPURITIES; PENTACENE; RUBRENE;
D O I
10.1002/adma.200802904
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Macroscopic single crystals of 4-hydroxycyanobenzene (4HCB) grown from solution exhibit reproducible and marked 3D mobility anisotropy. Air-gap OFET measurements along the planar axes a and b deliver average mobilities of 3 x 10(-2) and 6 x 10(-3) cm(2) V-1 s(-1), respectively. Spacecharge-limited current (SCLC) experiments reveal an average mobility along the c axis of 4 x 10(-6) cm(2) V-1 s(-1).
引用
收藏
页码:1835 / +
页数:6
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