Gas detection using low-temperature reduced graphene oxide sheets

被引:370
作者
Lu, Ganhua [1 ]
Ocola, Leonidas E. [2 ]
Chen, Junhong [1 ]
机构
[1] Univ Wisconsin, Dept Mech Engn, Milwaukee, WI 53211 USA
[2] Argonne Natl Lab, Ctr Nanoscale Mat, Argonne, IL 60439 USA
基金
美国国家科学基金会;
关键词
adsorption; annealing; charge exchange; electric sensing devices; gas sensors; graphene; hole density; nitrogen compounds; semiconductor materials; GRAPHITE OXIDE; FILMS; CONDUCTIVITY; REDUCTION; VAPOR;
D O I
10.1063/1.3086896
中图分类号
O59 [应用物理学];
学科分类号
摘要
We demonstrate a high-performance gas sensor using partially reduced graphene oxide (GO) sheets obtained through low-temperature step annealing (300 degrees C at maximum) in argon flow at atmospheric pressure. The electrical conductance of GO was measured after each heating cycle to interpret the level of reduction. The thermally reduced GO showed p-type semiconducting behavior in ambient conditions and were responsive to low-concentration NO2 diluted in air at room temperature. The sensitivity is attributed to the electron transfer from the reduced GO to adsorbed NO2, which leads to enriched hole concentration and enhanced electrical conduction in the reduced GO sheet.
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页数:3
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共 31 条
[21]   Electric field effect in atomically thin carbon films [J].
Novoselov, KS ;
Geim, AK ;
Morozov, SV ;
Jiang, D ;
Zhang, Y ;
Dubonos, SV ;
Grigorieva, IV ;
Firsov, AA .
SCIENCE, 2004, 306 (5696) :666-669
[22]   Aqueous Suspension and Characterization of Chemically Modified Graphene Sheets [J].
Park, Sungjin ;
An, Jinho ;
Piner, Richard D. ;
Jung, Inhwa ;
Yang, Dongxing ;
Velamakanni, Aruna ;
Nguyen, SonBinh T. ;
Ruoff, Rodney S. .
CHEMISTRY OF MATERIALS, 2008, 20 (21) :6592-6594
[23]   Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition [J].
Reina, Alfonso ;
Jia, Xiaoting ;
Ho, John ;
Nezich, Daniel ;
Son, Hyungbin ;
Bulovic, Vladimir ;
Dresselhaus, Mildred S. ;
Kong, Jing .
NANO LETTERS, 2009, 9 (01) :30-35
[24]   Reduced Graphene Oxide Molecular Sensors [J].
Robinson, Jeremy T. ;
Perkins, F. Keith ;
Snow, Eric S. ;
Wei, Zhongqing ;
Sheehan, Paul E. .
NANO LETTERS, 2008, 8 (10) :3137-3140
[25]   n-Type Behavior of Graphene Supported on Si/SiO2 Substrates [J].
Romero, Hugo E. ;
Shen, Ning ;
Joshi, Prasoon ;
Gutierrez, Humberto R. ;
Tadigadapa, Srinivas A. ;
Sofo, Jorge O. ;
Eklund, Peter C. .
ACS NANO, 2008, 2 (10) :2037-2044
[26]   Calling all chemists [J].
Ruoff, Rod .
NATURE NANOTECHNOLOGY, 2008, 3 (01) :10-11
[27]   Detection of individual gas molecules adsorbed on graphene [J].
Schedin, F. ;
Geim, A. K. ;
Morozov, S. V. ;
Hill, E. W. ;
Blake, P. ;
Katsnelson, M. I. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (09) :652-655
[28]   Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate) [J].
Stankovich, S ;
Piner, RD ;
Chen, XQ ;
Wu, NQ ;
Nguyen, ST ;
Ruoff, RS .
JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (02) :155-158
[29]   Transparent, conductive graphene electrodes for dye-sensitized solar cells [J].
Wang, Xuan ;
Zhi, Linjie ;
Muellen, Klaus .
NANO LETTERS, 2008, 8 (01) :323-327
[30]   TiO2-graphene nanocomposites.: UV-assisted photocatalytic reduction of graphene oxide [J].
Williams, Graeme ;
Seger, Brian ;
Kamat, Prashant V. .
ACS NANO, 2008, 2 (07) :1487-1491