Hydrothermal synthesis, crystal structure and luminescence property of a three dimensional Sm(III) coordination polymer with 2,5-pyridinedicarboxylic acid

被引：12

作者：

Gangu, Kranthi Kumar ^{[1
]}

Dadhich, Anima S. ^{[1
]}

Mukkamala, Saratchandra Babu ^{[1
]}

机构：

[1] GITAM Univ, Dept Chem, Visakhapatnam 530045, Andhra Pradesh, India

来源：

JOURNAL OF CHEMICAL SCIENCES | 2015年 / 127卷 / 12期

关键词：

Hydrothermal synthesis; coordination polymer; X-ray diffraction; samarium (III); luminescence property; LIGANDS; FRAMEWORKS; COMPLEXES; PHOTOLUMINESCENCE; SERIES;

D O I：

10.1007/s12039-015-0985-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel three dimensional coordination polymer [Sm(2,5-pydc)(NO3)(H2O)] a <...(H2O) (2,5-pydc = 2,5-pyridine dicarboxylate) (1) had been synthesized hydrothermally and characterized by elemental analysis, FT-IR and single-crystal X-ray diffraction analysis. This coordination polymer crystallized in the monoclinic space group P2/n with cell parameters a= 9.3610(4) , b= 8.3498(3) , c= 16.7159(8) , beta= 106.31(0)(a similar to), V= 1253.98(184) (3). Thermogravimetric analysis revealed that complex 1 is stable up to 400(a similar to)C which on photoexcitation at 365 nm exhibited yellow emission at 583 nm.

引用

页码：2225 / 2230

页数：6

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