Synthesis of homochiral 2-C-perfluoroalkyl substituted D- and L-riboses

被引：5

作者：

Eilitz, U

Böttcher, C

Hennig, L

Haas, A

Boyer, C

Burger, Y

机构：

[1] Univ Leipzig, Inst Organ Chem, D-04103 Leipzig, Germany

[2] Ruhr Univ Bochum, D-44780 Bochum, Germany

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2002年 / 115卷 / 02期

关键词：

stereoselective fluoroalkylation reactions; 2-C-heptafluoropropyl D-ribose; 2-C-nonafluorobutyl L-ribose;

D O I：

10.1016/S0022-1139(02)00042-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Homochiral 2-C-perfluoroalkyl substituted D- and L-riboses were synthesized via Barbier, Grignard and Ruppert type reactions. The influence of the size of the perfluoroalkyl groups, attached to C-2, on the furanose/pyranose as well as on the alpha-furanose/beta-furanose and alpha-pyranose/beta-pyranose ratio in solution was studied. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：149 / 154

页数：6

共 35 条

[1] THE COMPOSITION OF REDUCING SUGARS IN SOLUTION [J].