Synthesis of cyclopentenones: The new catalytic cocyclization reaction of alkyne, alkene, and carbon monoxide employing catalytic Co(acac)(2) and NaBH4

被引:75
作者
Lee, NY
Chung, YK
机构
[1] SEOUL NATL UNIV,COLL NAT SCI,DEPT CHEM,SEOUL 151742,SOUTH KOREA
[2] SEOUL NATL UNIV,COLL NAT SCI,CTR MOLEC CATALYSIS,SEOUL 151742,SOUTH KOREA
关键词
D O I
10.1016/0040-4039(96)00513-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new catalytic cycloaddition reaction of alkyne, alkene, and carbon monoxide employing catalytic amount of Co(acac)(2) and NaBH4 was developed for the synthesis of cyclopentenones. This catalytic system worked quite effectively for both intermolecular and intramolecular reactions. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:3145 / 3148
页数:4
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