Polymer-supported nitroxyl catalysts for selective oxidation of alcohols

被引：62

作者：

Ferreira, P

Hayes, W

Phillips, E

Rippon, D

Tsang, SC ^{[1
]}

机构：

[1] Univ Reading, Sch Chem, Reading RG6 6AD, Berks, England

[2] AH Marks & Co Ltd, Bradford BD12 9EJ, W Yorkshire, England

来源：

GREEN CHEMISTRY | 2004年 / 6卷 / 07期

关键词：

D O I：

10.1039/b406829g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel non-toxic poly(ethylene glycol)-supported 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) moieties are demonstrated to give an excellent interfacial catalysis for the selective oxidation of alcohols to the corresponding carbonyl species in biphasic media and investigation for the recovery of these new macromolecular catalysts via precipitation with diethyl ether after catalysis has also been briefly studied.

引用

页码：310 / 312

页数：3

共 26 条

[21] Oxidation process of water-soluble starch in TEMPO-mediated system [J].