Exploration of Chemically Cross-Linked Metal-Organic Frameworks

被引：31

作者：

Allen, C. A. ^{[1
]}

Cohen, S. M. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, San Diego, CA 92093 USA

来源：

INORGANIC CHEMISTRY | 2014年 / 53卷 / 13期

基金：

美国国家科学基金会;

关键词：

COORDINATION POLYMERS; NETWORKS; CRYSTAL; LINKING; GEL;

D O I：

10.1021/ic500951b

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学];

摘要：

A series of geometrically constrained, cross-linked benzene dicarboxylic acid (bdc) derivatives have been synthesized and incorporated into the canonical isoreticular metal-organic framework (IRMOF) lattice. Only certain cross-links, which allow for the proper relative orientation of the bdc subunits, form the desired IRMOF. Design criteria from these cross-linked ligands allowed for the rational design of two oligomeric ligands composed of three bdc monomers tethered together. These oligomeric ligands were also readily incorporated into an IRMOF lattice with a high degree of crystallinity and porosity, providing a new dimension to rational ligand design for metal-organic frameworks.

引用

页码：7014 / 7019

页数：6

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