An iron-catalysed synthesis of amides from nitriles and amines

被引:66
作者
Allen, C. Liana [1 ]
Lapkin, Alexei A. [2 ]
Williams, Jonathan M. J. [1 ]
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Univ Bath, Dept Chem Engn, Bath BA2 7AY, Avon, England
基金
英国工程与自然科学研究理事会;
关键词
UNACTIVATED NITRILES; HYDROGEN-PEROXIDE; EFFICIENT; BENZYLAMINE; AMIDATION; OXIDATION; HYDRATION; OXIDANT; SYSTEM;
D O I
10.1016/j.tetlet.2009.05.021
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The cheap, commercially available iron complex, Fe(NO3)(3)center dot 9H(2)O, has been used to catalyse the formation of amides by the addition of amines to nitriles. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4262 / 4264
页数:3
相关论文
共 28 条
[1]   FeCl3-catalyzed Ritter reaction. Synthesis of amides [J].
Anxionnat, Bruno ;
Guerinot, Amandine ;
Reymond, Sebastien ;
Cossy, Janine .
TETRAHEDRON LETTERS, 2009, 50 (26) :3470-3473
[2]  
Beckwith A. L. J., 1970, CHEM AMIDES
[3]   An Improved Iron-Catalyzed Epoxidation of Aromatic and Aliphatic Olefins with Hydrogen Peroxide as Oxidant [J].
Bitterlich, Bianca ;
Schroeder, Kristin ;
Tse, Man Kin ;
Beller, Matthias .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (29) :4867-4870
[4]   Iron-catalyzed reactions in organic synthesis [J].
Bolm, C ;
Legros, J ;
Le Paih, J ;
Zani, L .
CHEMICAL REVIEWS, 2004, 104 (12) :6217-6254
[5]  
BURKARD W, 1980, Patent No. 4210754
[6]  
CADIERNO V, 2008, J CHEM EUR J, V14, P6601
[7]   Efficient preparation of terminal conjugated dienes by coupling of dienol phosphates with Grignard reagents under iron catalysis [J].
Cahiez, Gerard ;
Habiak, Vanessa ;
Gager, Olivier .
ORGANIC LETTERS, 2008, 10 (12) :2389-2392
[8]   Platinum catalysed hydrolytic amidation of unactivated nitriles [J].
Cobley, CJ ;
van den Heuvel, M ;
Abbadi, A ;
de Vries, JG .
TETRAHEDRON LETTERS, 2000, 41 (14) :2467-2470
[9]   Iron-catalyzed N-arylations of Amides [J].
Correa, Arkaitz ;
Elmore, Simon ;
Bolm, Carsten .
CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (12) :3527-3529
[10]   NITRILE GROUPS .4. THE CATALYZED REACTION OF NITRILES WITH AMINES IN WATER [J].
DEBENNEVILLE, PL ;
LEVESQUE, CL ;
EXNER, LJ ;
HERTZ, E .
JOURNAL OF ORGANIC CHEMISTRY, 1956, 21 (10) :1072-1076