Balancing framework densification with charged, halogen-bonded-π-conjugated linkages:: [PPh4]2{[E-TTF-I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF-I]2{[EDT-TTF-I][Re6Se8(CN)6]}

被引：36

作者：

Ranganathan, Anupama

El-Ghayoury, Abdelkrim

Meziere, Cecile

Harte, Etienne

Clerac, Rodolphe

Batail, Patrick

机构：

[1] Univ Angers, UMR 6200 CNRS, Lab Chim Ingn Mol & Mat Angers, F-49045 Angers, France

[2] Ctr Rech Paul Pascal, CNRS, UPR 8641, F-33600 Pessac, France

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 27期

关键词：

D O I：

10.1039/b600159a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ionic character of a set of two redox linkages and strong, directional halogen bonding at the organic - inorganic interface compromise to produce two materials sharing a common two-dimensional net, eventually extended in a third dimension, although two of the six symmetrical halogen bond acceptors ultimately remain uninvolved as a result of charge densification.

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页码：2878 / 2880

页数：3

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