Angle-dependent ultraviolet photoelectron spectroscopy of sputter cleaned polycrystalline noble metals

Polycrystalline noble metal films are commonly used in practical applications across a variety of different fields. However, the surface electronic structure of the noble metals has primarily only been studied on single crystal substrates. In addition, sputter cleaned polycrystalline noble metal films are commonly used substrates in ultraviolet photoelectron spectroscopy (UPS) studies, but have yet to be systematically studied in terms of their photoemission anisotropy. The angle-dependence of the valence band spectra of sputter cleaned polycrystalline Au, Ag and Cu were studied using angle-resolved UPS. It is found that the photoemission is anisotropic with respect to photoelectron take-off angle. The results for Ag and Cu are in good agreement with previous reports of surface d-band narrowing in polycrystalline noble metal films. However, significant anisotropies in the d-band, s-band and Fermi edge of sputter cleaned Au are observed, which cannot be attributed to surface d-band narrowing alone. The unusual results for Au are attributed to drastic changes in the film morphology near the surface as a result of sputter cleaning. (C) 2009 Elsevier B.V. All rights reserved.