Molecular modelling of electron transfer systems by noncovalently linked porphyrin-acceptor pairing

被引：192

作者：

Hayashi, T ^{[1
]}

Ogoshi, H ^{[1
]}

机构：

[1] KYOTO UNIV,GRAD SCH ENGN,DEPT SYNTHET CHEM & BIOL CHEM,KYOTO 60601,JAPAN

来源：

CHEMICAL SOCIETY REVIEWS | 1997年 / 26卷 / 05期

关键词：

D O I：

10.1039/cs9972600355

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the respiratory system, electron carriers such as ubiquinone and cytochrome c play an important role in the electron transfer (ET) reaction between oxidoreductases embedded in the mitochondrial membrane, This review focuses on a strategy for constructing porphyrin-electron acceptor pairs via specific interactions and the evaluation of ET in these systems, Particularly, the molecular recognition of ubiquinone analogues by porphyrin host molecules and the mimicking of protein-protein complexation using myoglobin reconstituted with a synthetic porphyrin are reviewed, and the characteristics of the photoinduced ET within noncovalently linked complexes are discussed.

引用

页码：355 / 364

页数：10

共 42 条

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