Highly efficient Rh(I)-catalyzed asymmetric hydrogenation of enamines using monodente spiro phosphonite ligands

被引:71
作者
Hou, Guo-Hua
Xie, Jian-Hua
Wang, Li-Xin
Zhou, Qi-Lin [1 ]
机构
[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
[2] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
关键词
D O I
10.1021/ja0644778
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A highly enantioselective hydrogenation of nonfunctionalized enamines has been developed by using rhodium complexes of chiral spiro phosphonite ligands, providing chiral tertiary amines in excellent enantioselectivities. Copyright © 2006 American Chemical Society.
引用
收藏
页码:11774 / 11775
页数:2
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