Chiral phosphabarrelene ligands: Synthesis and evaluation in rhodium-catalyzed asymmetric hydrogenation

被引:23
作者
Breit, Bernhard [1 ]
Fuchs, Evelyn [1 ]
机构
[1] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany
来源
SYNTHESIS-STUTTGART | 2006年 / 13期
关键词
asymmetric catalysis; hydrogenation; ligands; phosphorus; rhodium;
D O I
10.1055/s-2006-942425
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first chiral and enantiomerically pure monodentate and bidentate phosphabarrelene ligands have been prepared and their potential in rhodium-catalyzed asymmetric hydrogenation has been evaluated.
引用
收藏
页码:2121 / 2128
页数:8
相关论文
共 14 条
[1]  
[Anonymous], ANGEW CHEM
[2]   Phosphabarrelene-rhodium complexes as highly active catalysts for isomerization free hydroformylation of internal alkenes [J].
Breit, B ;
Fuchs, E .
CHEMICAL COMMUNICATIONS, 2004, (06) :694-695
[3]  
Breit B, 2001, CHEM-EUR J, V7, P3106, DOI 10.1002/1521-3765(20010716)7:14<3106::AID-CHEM3106>3.0.CO
[4]  
2-Y
[5]  
DIMROTH K, 2004, ORG SYNTH COLL, V5, P1135
[6]   STRUCTURAL SYSTEMATICS .3. GEOMETRY DEFORMATIONS IN TRIPHENYLPHOSPHINE FRAGMENTS - A TEST OF BONDING THEORIES IN PHOSPHINE COMPLEXES [J].
DUNNE, BJ ;
MORRIS, RB ;
ORPEN, AG .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, :653-661
[7]  
MAERKL G, 1971, TETRAHEDRON LETT, V12, P1249
[8]   Nonvolatile Me3P-like P-donor ligand:: Synthesis and properties of 4-phenyl-1-phospha-4-silabicyclo[2.2.2]octane [J].
Ochida, A ;
Hara, K ;
Ito, H ;
Sawamura, M .
ORGANIC LETTERS, 2003, 5 (15) :2671-2674
[9]   STRUCTURAL SYSTEMATICS - ROLE OF P-A SIGMA-STAR ORBITALS IN METAL-PHOSPHORUS PI-BONDING IN REDOX-RELATED PAIRS OF M-PA3 COMPLEXES (A = R, AR, OR, R = ALKYL) [J].
ORPEN, AG ;
CONNELLY, NG .
ORGANOMETALLICS, 1990, 9 (04) :1206-1210
[10]  
Reetz MT, 2003, CHIM OGGI, V21, P5