Synthesis and first application of a new family of monophosphine ferrocene ligands (MOPF)

被引：56

作者：

Pedersen, HL ^{[1
]}

Johannsen, M ^{[1
]}

机构：

[1] Tech Univ Denmark, Dept Organ Chem, DK-2800 Lyngby, Denmark

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 24期

关键词：

D O I：

10.1039/a908921g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new family of monophosphine ferrocene ligands (MOPF) has been synthesised in two steps from an optically pure ferrocenyl sulfoxide and the first preliminary studies employing these ligands in asymmetric hydrosilylation of styrene are presented.

引用

页码：2517 / 2518

页数：2

共 22 条

[1] Ir-catalysed allylic substitution: mechanistic aspects and asymmetric synthesis with phosphorus amidites as ligands
Bartels, B
Helmchen, G
[J]. CHEMICAL COMMUNICATIONS, 1999, (08) : 741 - 742
[2] Atropo-enantioselective synthesis of an axially chiral C1-symmetric phosphine ligand and its application in the asymmetric hydrosilylation of styrenes
Bringmann, G
Wuzik, A
Breuning, M
Henschel, P
Peters, K
Peters, EM
[J]. TETRAHEDRON-ASYMMETRY, 1999, 10 (15) : 3025 - 3031
[3] Highly enantioselective catalytic conjugate addition and tandem conjugate addition - Aldol reactions of organozinc reagents
Feringa, BL
Pineschi, M
Arnold, LA
Imbos, R
de Vries, AHM
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (23) : 2620 - 2623
[4] New homochiral ligands bearing nonstereogenic chirotopic centers.: Lithiated N,N′-dialkylureas as chiral bases and sterically crowded phosphines for asymmetric catalysis
Graf, CD
Malan, C
Harms, K
Knochel, P
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (15) : 5581 - 5588
[5] ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE TRANSITION-METAL COMPLEXES .6. PRACTICAL ASYMMETRIC-SYNTHESIS OF 1,1'-BINAPHTHYLS VIA ASYMMETRIC CROSS-COUPLING WITH A CHIRAL [(ALKOXYALKYL)FERROCENYL]MONOPHOSPHINE NICKEL-CATALYST
HAYASHI, T
HAYASHIZAKI, K
KIYOI, T
ITO, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (24) : 8153 - 8156
[6] Enantioselective synthesis of sulfur-containing 1,2-disubstituted ferrocenes
Hua, DH
Lagneau, NM
Chen, Y
Robben, PM
Clapham, G
Robinson, PD
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (14) : 4508 - 4509
[7] PALLADIUM-CATALYZED ASYMMETRIC HYDROSILYLATION OF STYRENES WITH A NEW CHIRAL MONODENTATE PHOSPHINE LIGAND
KITAYAMA, K
UOZUMI, Y
HAYASHI, T
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (15) : 1533 - 1534
[8] Asymmetric synthesis of monodentate phosphine ligands based on chiral η6-Cr[arene] templates
Nelson, SG
Hilfiker, MA
[J]. ORGANIC LETTERS, 1999, 1 (09) : 1379 - 1382
[9] ASYMMETRIC REACTIONS CATALYZED BY CHIRAL METAL-COMPLEXES .40. ASYMMETRIC HYDROSILYLATION OF CYCLOPENTADIENE AND STYRENE WITH CHLOROSILANES CATALYZED BY PALLADIUM COMPLEXES OF CHIRAL (BETA-N-SULFONYLAMINOALKYL)PHOSPHINES
OKADA, T
MORIMOTO, T
ACHIWA, K
[J]. CHEMISTRY LETTERS, 1990, (06) : 999 - 1002
[10] Highly enantioselective palladium-catalyzed hydrosilylation of norbornene with trichlorosilane using ferrocenyl ligands
Pioda, G
Togni, A
[J]. TETRAHEDRON-ASYMMETRY, 1998, 9 (21) : 3903 - 3910

← 1 2 3 →