Metal bis{(trifluoromethyl)sulfonyl}amide complexes: highly efficient Friedel-Crafts acylation catalysts

被引：103

作者：

Earle, MJ

Hakala, U

McAuley, BJ

Nieuwenhuyzen, M

Ramani, A

Seddon, KR

机构：

[1] Queens Univ Belfast, QUILL Ctr, Belfast BT9 5AG, Antrim, North Ireland

[2] Univ Helsinki, Fac Sci, Dept Chem, Lab Organ Chem, FIN-00014 Helsinki, Finland

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 12期

关键词：

D O I：

10.1039/b403650f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A range of metal bis{(trifluoromethyl)sulfonyl}amide complexes, including many unreported ones, have been synthesised, most of which have been found to be excellent Friedel-Crafts acylation catalysts in the absence of solvent; these reactions have also been carried out in ionic liquids, which allow the catalysts to be recycled and reused.

引用

页码：1368 / 1369

页数：2

共 16 条

[1] Adams CJ, 1998, CHEM COMMUN, P2097
[2] [Anonymous], [No title captured]
[3] *BRUK AXS, 1998, SAINT NT PROGR DAT C
[4] Lanthanide bis(trifluoromethylsulfonyl)amides vs. trifluoromethylsulfonates as catalysts for Friedel-Crafts acylations
Duris, F
Barbier-Baudry, D
Dormond, A
Desmurs, JR
Bernard, JM
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 188 (1-2) : 97 - 104
[5] Earle M., 2002, [No title captured], Patent No. [WO 02072260, 02072260]
[6] Counterion effects in indium-catalysed aromatic electrophilic substitution reactions
Frost, CG
Hartley, JP
Griffin, D
[J]. TETRAHEDRON LETTERS, 2002, 43 (27) : 4789 - 4791
[7] Magnesium trifluoromethanesulfonimide(triflimide) promoted substitution reactions of allylic and benzylic acetates. Magnesium triflimide as a substitute for magnesium perchlorate.
Grieco, PA
Handy, ST
[J]. TETRAHEDRON LETTERS, 1997, 38 (15) : 2645 - 2648
[8] Ishihara K, 1996, SYNLETT, P839
[9] Lewis acid-catalyzed Friedel-Crafts acylation reaction using carboxylic acids as acylating agents
Kawamura, M
Cui, DM
Hayashi, T
Shimada, S
[J]. TETRAHEDRON LETTERS, 2003, 44 (42) : 7715 - 7717
[10] MATAUO J, 2000, SYNLETT, P403

← 1 2 →