Orientation and bonding of 4,4′-biphenyldiisocyanide

被引：14

作者：

Caruso, AN

Rajesh, R

Gallup, G

Redepenning, J

Dowben, PA

机构：

[1] Univ Nebraska, Brace Lab 116, Dept Phys & Astron, Lincoln, NE 68588 USA

[2] Univ Nebraska, Ctr Mat Res & Anal, Behlen Lab Phys, Lincoln, NE 68588 USA

[3] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2004年 / 108卷 / 22期

关键词：

D O I：

10.1021/jp037710m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The orientation and bonding of 4,4'-biphenyldiisocyanide (BPDI) adsorbed by solution on Au(111) has been examined by polarization dependent photoemission and inverse photoemission. The highest occupied molecular orbital to lowest unoccupied molecular orbital gap for BPDI is about 10.8 eV, with the Fermi level nearly midgap. The electronic structure of isocyano-functionalized polyphenyls suggests that they are better dielectrics than thiol-functionalized polyphenyls.

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页码：6910 / 6914

页数：5

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