Polymeric (μ2-nitrato-κ2O:O′)(μ2-nitrato-κ2O:O)(μ4-pyridinium-4-thiolato-κ4S:S:S:S)disilver(I)

被引：5

作者：

Chen, YB ^{[1
]}

Kang, Y ^{[1
]}

Qin, YY ^{[1
]}

Li, ZJ ^{[1
]}

Cheng, JK ^{[1
]}

Yao, YG ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷

关键词：

D O I：

10.1107/S0108270104006936

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Ag-2(NO3)(2)(C5H5NS)](n), was obtained from the reaction of silver nitrate with bis(4-pyridyl) disulfide (4-PDS) in a mixture of ethanol and water, which suggests that the disulfide bond of 4-PDS can be cleaved under mild conditions. The structure of the title compound is a two-dimensional infinite array in which the asymmetric unit contains two Ag atoms, a pyridinium-4-thiolate molecule and two nitrate groups. Each pyridinium-4-thiolate molecule acts as a mu(4) bridge, linking four Ag atoms, with Ag-S bond distances of 2.4870(19), 2.5791(19), 2.5992(19) and 2.848(2) Angstrom. The Ag...Ag distances lie in the range 2.889 (2)-3.049 (1) Angstrom.

引用

收藏

页码：M263 / M265

页数：3

相关论文

共 30 条

[1] THIOLATO-COMPLEXES OF THE TRANSITION-METALS [J].

BLOWER, PJ ;

DILWORTH, JR .

COORDINATION CHEMISTRY REVIEWS, 1987, 76 :121-185

[2] Carbidohexarhenate cluster cores bicapped by mercury with acetate or thiolate ligands [J].

Brand, U ;

Shapley, JR .

INORGANIC CHEMISTRY, 2000, 39 (01) :32-36

[3]

*BRUK AXS INC, 2001, SHELXTL VERS 6 12

[4] 1-DIMENSIONAL, 2-DIMENSIONAL, AND 3-DIMENSIONAL POLYMERIC FRAMES IN THE COORDINATION CHEMISTRY OF AGBF4 WITH PYRAZINE - THE FIRST EXAMPLE OF 3 INTERPENETRATING 3-DIMENSIONAL TRICONNECTED NETS [J].

CARLUCCI, L ;

CIANI, G ;

PROSERPIO, DM ;

SIRONI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (16) :4562-4569

[5] Reactivity of organometallic molybdate toward lanthanide cations. Synthesis and structure of polynuclear lanthanide-molybdate complexes [J].

Hashimoto, M ;

Takata, M ;

Yagasaki, A .

INORGANIC CHEMISTRY, 2000, 39 (16) :3712-+

[6] Controlled assembly based on multibridging thiolate ligands: New polymeric silver(I) complexes with one-dimensional chain and three-dimensional network structures [J].

Hong, MC ;

Su, WP ;

Cao, R ;

Zhang, WJ ;

Li, JX .

INORGANIC CHEMISTRY, 1999, 38 (03) :600-+

[7]

Kato M, 2002, ANGEW CHEM INT EDIT, V41, P3183, DOI 10.1002/1521-3773(20020902)41:17<3183::AID-ANIE3183>3.0.CO

[8]

2-A

[9] Six-coordinate and five-coordinate FeII(CN)2(CO)x thiolate complexes (x=1, 2):: Synthetic advances for iron sites of [NiFe] hydrogenases [J].

Liaw, WF ;

Lee, JH ;

Gau, HB ;

Chen, CH ;

Jung, SJ ;

Hung, CH ;

Chen, WY ;

Hu, CH ;

Lee, GH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (08) :1680-1688

[10] Pyridine-2-thione derivatives of silver(I) and mercury(II): crystal structures of dimeric [bis(diphenylphosphino)methane][(1-oxopyridine-2-thionato)silver(I), [2-(benzylsulfanyl)pyridine 1-oxide]dichloromercury(II) and phenyl(pyridine-2-thionato)mercury(II) [J].

Lobana, TS ;

Paul, S ;

Castineiras, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (11) :1819-1824