Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal-Organic Frameworks at Room Temperature

被引：474

作者：

Hamon, Lomig ^{[1
]}

Serre, Christian ^{[2
]}

Devic, Thomas ^{[2
]}

Loiseau, Thierry ^{[2
]}

Millange, Franck ^{[2
]}

Ferey, Gerard ^{[2
]}

De Weireld, Guy ^{[1
]}

机构：

[1] Fac Polytech Mons, Lab Thermodynam, B-7000 Mons, Belgium

[2] Univ Versailles St Quentin En Yuelines, CNRS, UMR 8180, Inst Lavoisier, F-78035 Versailles, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 25期

关键词：

MICROPOROUS COORDINATION POLYMERS; GIANT PORES; CARBON-DIOXIDE; CO2; BENZENEDICARBOXYLATE; STORAGE; SOLIDS; METHANE; DESIGN;

D O I：

10.1021/ja901587t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogen sulfide gravimetric isotherm adsorption measurements were carried out on MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) metal-organic frameworks (MOFs). A two-step adsorption mechanism related to a breathing effect was observed for MIL-53 terephthalate-based MOFs. Methane adsorption measurements highlighted the regenerability of MIL-53(Al, Cr) and MIL-47(V) MOFs after H2S treatment, whereas MIL-100 and MIL-101 CH4 adsorption capacities were significantly decreased.

引用

页码：8775 / +

页数：4

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