Easy interpretation of optical two-dimensional correlation spectra

被引:107
作者
Lazonder, Kees [1 ]
Pshenichnikov, Maxim S. [1 ]
Wiersma, Douwe A. [1 ]
机构
[1] Univ Groningen, Ultrafast Laser & Spect Lab, Ctr Mat Sci, NL-9747 AG Groningen, Netherlands
关键词
D O I
10.1364/OL.31.003354
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We demonstrate that the value of the underlying frequency-frequency correlation function can be retrieved from a two-dimensional optical correlation spectrum through a simple relationship. The proposed method yields both intuitive clues and a quantitative measure of the dynamics of the system. The technique is applied to studying the effects of temperature and phase changes on liquid-glass solvent dynamics. (c) 2006 Optical Society of America
引用
收藏
页码:3354 / 3356
页数:3
相关论文
共 15 条
[1]   NON-MARKOVIAN THEORY OF NON-LINEAR-OPTICAL PHENOMENA ASSOCIATED WITH THE EXTREMELY FAST RELAXATION IN CONDENSED MATTER [J].
AIHARA, M .
PHYSICAL REVIEW B, 1982, 25 (01) :53-60
[2]   FEMTOSECOND ELECTRONIC DEPHASING IN LARGE MOLECULES IN SOLUTION USING MODE SUPPRESSION [J].
BARDEEN, CJ ;
SHANK, CV .
CHEMICAL PHYSICS LETTERS, 1993, 203 (5-6) :535-539
[3]   Two-dimensional spectroscopy of electronic couplings in photosynthesis [J].
Brixner, T ;
Stenger, J ;
Vaswani, HM ;
Cho, M ;
Blankenship, RE ;
Fleming, GR .
NATURE, 2005, 434 (7033) :625-628
[4]   System-bath correlation function probed by conventional and time-gated stimulated photon echo [J].
deBoeij, WP ;
Pshenichnikov, MS ;
Wiersma, DA .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (29) :11806-11823
[5]   Ultrafast hydrogen-bond dynamics in the infrared spectroscopy of water [J].
Fecko, CJ ;
Eaves, JD ;
Loparo, JJ ;
Tokmakoff, A ;
Geissler, PL .
SCIENCE, 2003, 301 (5640) :1698-1702
[6]   The two-dimensional IR nonlinear spectroscopy of a cyclic penta-peptide in relation to its three-dimensional structure [J].
Hamm, P ;
Lim, M ;
DeGrado, WF ;
Hochstrasser, RM .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1999, 96 (05) :2036-2041
[7]   Two-dimensional femtosecond spectroscopy [J].
Jonas, DM .
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2003, 54 :425-463
[8]   Molecular dynamics simulation study of N-methylacetamide in water.: II.: Two-dimensional infrared pump-probe spectra [J].
Kwac, K ;
Cho, MH .
JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (04) :2256-2263
[9]  
Mukamel S, 1995, PRINCIPLES NONLINEAR, P209
[10]   Two-dimensional line-shape analysis of photon-echo signal [J].
Okumura, K ;
Tokmakoff, A ;
Tanimura, Y .
CHEMICAL PHYSICS LETTERS, 1999, 314 (5-6) :488-495