Decrease in the leakage current density of Si-based metal-oxide-semiconductor diodes by cyanide treatment

被引:39
作者
Asano, A
Asuha
Maida, O
Todokoro, Y
Kobayashi, H
机构
[1] Osaka Univ, Inst Sci & Ind Res, Osaka 5670047, Japan
[2] Osaka Univ, Japan Sci & Technol Corp, CREST, Osaka 5670047, Japan
[3] Matsushita Elect Ind Co Ltd, Semicond Co, Technol Liaison Off, Minato Ku, Tokyo 1058586, Japan
关键词
D O I
10.1063/1.1484249
中图分类号
O59 [应用物理学];
学科分类号
摘要
Crown-ether cyanide treatment, which includes the immersion of Si in KCN solutions containing 18-crown-6 molecules, is found to greatly decrease the leakage current density of Si-based metal-oxide-semiconductor (MOS) diodes. The decrease by one order of magnitude for the single crystalline Si-based MOS diodes is attributable to the elimination of Si/SiO2 interface states by reaction with cyanide ions and formation of Si-CN bonds. The reduction in the leakage current density by two orders of magnitude is caused for polycrystalline Si-based MOS diodes, and this decrease is attributed to the passivation of trap states in poly-Si as well as the interface states. (C) 2002 American Institute of Physics.
引用
收藏
页码:4552 / 4554
页数:3
相关论文
共 18 条
[1]   ESR CENTERS, INTERFACE STATES, AND OXIDE FIXED CHARGE IN THERMALLY OXIDIZED SILICON WAFERS [J].
CAPLAN, PJ ;
POINDEXTER, EH ;
DEAL, BE ;
RAZOUK, RR .
JOURNAL OF APPLIED PHYSICS, 1979, 50 (09) :5847-5854
[2]   Experimental evidence of Si-H bond energy variation at SiO2-Si interface [J].
Cheng, KG ;
Lee, J ;
Lyding, JW .
APPLIED PHYSICS LETTERS, 2000, 77 (21) :3388-3390
[3]  
*CRC, 1995, CRC HDB CHEM PHYS, P951
[4]   THEORY OF TUNNELING INTO INTERFACE STATES [J].
FREEMAN, LB ;
DAHLKE, WE .
SOLID-STATE ELECTRONICS, 1970, 13 (11) :1483-+
[5]   HYDROGEN MODEL FOR RADIATION-INDUCED INTERFACE STATES IN SIO2-ON-SI STRUCTURES - A REVIEW OF THE EVIDENCE [J].
GRISCOM, DL .
JOURNAL OF ELECTRONIC MATERIALS, 1992, 21 (07) :763-767
[6]   ANNEALING OF SURFACE-STATES IN POLYCRYSTALLINE-SILICON-GATE CAPACITORS [J].
HICKMOTT, TW .
JOURNAL OF APPLIED PHYSICS, 1977, 48 (02) :723-733
[7]   Passivation of trap states in polycrystalline Si by cyanide treatments [J].
Kanazaki, E ;
Yoneda, K ;
Todokoro, Y ;
Nishitani, M ;
Kobayashi, H .
SOLID STATE COMMUNICATIONS, 1999, 113 (04) :195-199
[8]   Studies on interface states at ultrathin SiO2/Si(100) interfaces by means of x-ray photoelectron spectroscopy under biases and their passivation by cyanide treatment [J].
Kobayashi, H ;
Asano, A ;
Asada, S ;
Kubota, T ;
Yamashita, Y ;
Yoneda, K ;
Todokoro, Y .
JOURNAL OF APPLIED PHYSICS, 1998, 83 (04) :2098-2103
[9]   Improvement of electrical characteristics of (indium-tin oxide silicon oxide polycrystalline n-Si) solar cells by a KCN treatment [J].
Kobayashi, H ;
Tachibana, S ;
Nakato, Y ;
Yoneda, K .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (08) :2893-2897
[10]   Decrease in gap states at ultrathin SiO2/Si interfaces by crown-ether cyanide treatment [J].
Kobayashi, H ;
Asano, A ;
Takahashi, M ;
Yoneda, K ;
Todokoro, Y .
APPLIED PHYSICS LETTERS, 2000, 77 (26) :4392-4394