Crown-ether cyanide treatment, which includes the immersion of Si in KCN solutions containing 18-crown-6 molecules, is found to greatly decrease the leakage current density of Si-based metal-oxide-semiconductor (MOS) diodes. The decrease by one order of magnitude for the single crystalline Si-based MOS diodes is attributable to the elimination of Si/SiO2 interface states by reaction with cyanide ions and formation of Si-CN bonds. The reduction in the leakage current density by two orders of magnitude is caused for polycrystalline Si-based MOS diodes, and this decrease is attributed to the passivation of trap states in poly-Si as well as the interface states. (C) 2002 American Institute of Physics.
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CAPLAN, PJ
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POINDEXTER, EH
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DEAL, BE
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DEAL, BE
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RAZOUK, RR
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FAIRCHILD CAMERA & INSTRUMENT CORP, RES & DEV LAB, PALO ALTO, CA 94304 USAFAIRCHILD CAMERA & INSTRUMENT CORP, RES & DEV LAB, PALO ALTO, CA 94304 USA
CAPLAN, PJ
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POINDEXTER, EH
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DEAL, BE
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RAZOUK, RR
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