Heterogeneous photocatalysts in organic synthesis

被引：49

作者：

Cherevatskaya, M. ^{[1
]}

Koenig, B. ^{[1
]}

机构：

[1] Univ Regensburg, Fac Chem & Pharm, D-93049 Regensburg, Germany

来源：

RUSSIAN CHEMICAL REVIEWS | 2014年 / 83卷 / 03期

关键词：

SEMICONDUCTOR PHOTOCATALYSIS; C-C; ELECTROPHILIC ALKENES; HETEROCYCLIC BASES; CADMIUM-SULFIDE; TIO2; ALKYLATION; PHOTOREDOX; AMINES; FUNCTIONALIZATION;

D O I：

10.1070/RC2014v083n03ABEH004427

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The review deals with the application of inorganic semiconductors in organic synthesis. Although the majority of reported reactions still aim at the photocatalytic decomposition of organic compounds, the number of examples in synthetic applications is growing. The principal mechanisms of heterogeneous semiconductor photocatalysis are considered and examples illustrating the use of inorganic semiconductors in organic synthesis are given. The discussion is arranged according to the required excitation wavelength (UV or visible light) and to the new bond that is formed (carbon carbon or carbon heteroatom bond).

引用

页码：183 / 195

页数：13

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