Complexation of Nitrous Oxide by Frustrated Lewis Pairs

被引：264

作者：

Otten, Edwin ^{[1
]}

Neu, Rebecca C. ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 29期

基金：

加拿大自然科学与工程研究理事会;

关键词：

N BOND-CLEAVAGE; 3-COORDINATE MOLYBDENUM(III); INSERTION REACTIONS; DINITROGEN OXIDE; ATOM TRANSFER; REACTIVITY; N2O; ACTIVATION; OXIDATION; HYDRIDE;

D O I：

10.1021/ja904377v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Frustrated Lewis pairs comprised of a basic yet sterically encumbered phosphine with boron Lewis acids bind nitrous oxide to give intact PNNOB linkages. The synthesis, structure, and bonding of these species are described.

引用

页码：9918 / +

页数：3

共 47 条

[1] FORMATION AND REACTIONS OF [(NH3]5RUN2O2+] [J].

ARMOR, JN ;

TAUBE, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (24) :6874-&

[2] Reduction of Nitrous Oxide to Dinitrogen by a Mixed Valent Tricopper-Disulfido Cluster [J].

Bar-Nahum, Itsik ;

Gupta, Aalo K. ;

Huber, Stefan M. ;

Ertem, Mehmed Z. ;

Cramer, Christopher J. ;

Tolman, William B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (08) :2812-+

[3] Stabilised phosphazides [J].

Bebbington, Magnus W. P. ;

Bourissou, Didier .

COORDINATION CHEMISTRY REVIEWS, 2009, 253 (9-10) :1248-1261

[4] REACTIONS BETWEEN NITROSYLPENTAAMMINERUTHENIUM(II) AND HYDROXYLAMINE OR HYDRAZINE - FORMATION OF (DINITROGEN OXIDE)PENTAAMMINERUTHENIUM(II) [J].

BOTTOMLE.F ;

CRAWFORD, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (26) :9092-9095

[5] MODE OF BONDING OF DINITROGEN OXIDE (NITROUS-OXIDE) IN (DINITROGEN OXIDE)PENTAAMMINERUTHENIUM [J].

BOTTOMLEY, F ;

BROOKS, WVF .

INORGANIC CHEMISTRY, 1977, 16 (02) :501-502

[6] CYCLOPENTADIENYLMETAL OXIDES [J].

BOTTOMLEY, F .

POLYHEDRON, 1992, 11 (14) :1707-1731

[7] Metal-free catalytic hydrogenation [J].

Chase, Preston A. ;

Welch, Gregory C. ;

Jurca, Titel ;

Stephan, Douglas W. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (42) :8050-8053

[8] N2O reduction by the μ4-sulfide-bridged tetranuclear CuZ cluster active site [J].

Chen, P ;

Gorelsky, SI ;

Ghosh, S ;

Solomon, EI .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (32) :4132-4140

[9] On the origin of selective nitrous oxide N-N bond cleavage by three-coordinate molybdenum(III) complexes [J].

Cherry, JPF ;

Johnson, AR ;

Baraldo, LM ;

Tsai, YC ;

Cummins, CC ;

Kryatov, SV ;

Rybak-Akimova, EV ;

Capps, KB ;

Hoff, CD ;

Haar, CM ;

Nolan, SP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (30) :7271-7286

[10] The syntheses and structures of lithium phosphinimide and phosphinimine complexes [J].

Courtenay, S ;

Wei, PR ;

Stephan, DW .

CANADIAN JOURNAL OF CHEMISTRY, 2003, 81 (12) :1471-1476

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