Palladium-indium mediated Barbier-type allylation of aldehydes with allenes

被引:75
作者
Anwar, U [1 ]
Grigg, R [1 ]
Rasparini, M [1 ]
Savic, V [1 ]
Sridharan, V [1 ]
机构
[1] Univ Leeds, Sch Chem, Mol Innovat Divers & Automated Synth Ctr, Leeds LS2 9JT, W Yorkshire, England
关键词
D O I
10.1039/b001457p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new allylation reaction of carbonyl compounds using allenes is described; homoallylic alcohols were obtained in moderate to good yields from aryl iodides, allenes and carbonyl compounds and an excellent diastereoselection was exhibited when 2-hydroxycyclohexanone was employed.
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页码:645 / 646
页数:2
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