Catalytic activity of rare-earth-supported catalysts in Friedel-Crafts acylations

被引:11
作者
Baudry-Barbier, D [1 ]
Dormond, A [1 ]
Duriau-Montagne, F [1 ]
机构
[1] Univ Bourgogne 1, Fac Sci Gabriel, Lab Synth & Electrosynth Organomet, LSEO,UMR 5632 CNRS, F-21000 Dijon, France
关键词
Friedel-Crafts; acylation; supported catalysis; rare-earth compounds; lanthanides;
D O I
10.1016/S1381-1169(99)00178-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Friedel-Crafts acylations are catalysed by rare-earth-supported catalysts. The preparation, characterization and performance of these solid catalysts in a test acylation reaction and in a variety of syntheses of aromatic ketones are reported. In contrast to the reactions using AlCl3, the experimental conditions are non-polluting and the final work-up does not require any aqueous treatment. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:215 / 224
页数:10
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