Selective epoxidations involving anionic peroxotungsten compounds generated in situ on layered double hydroxides with various polarities

被引:49
作者
Sels, BF [1 ]
DeVos, DE [1 ]
Jacobs, PA [1 ]
机构
[1] KATHOLIEKE UNIV LEUVEN,CTR CATALYSIS & SURFACE SCI,B-3001 HEVERLEE,BELGIUM
关键词
D O I
10.1016/0040-4039(96)01955-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
WO42--exchanged LDH catalyses the epoxidation of simple olefins and allylic alcohols. Substrate reactivity, chemo- and regioselectivity vary markedly with the polarity of the peroxotungstate environment. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:8557 / 8560
页数:4
相关论文
共 15 条
[1]   REINVESTIGATION OF EPOXIDATION USING TUNGSTEN-BASED PRECURSORS AND HYDROGEN-PEROXIDE IN A BIPHASE MEDIUM [J].
AUBRY, C ;
CHOTTARD, G ;
PLATZER, N ;
BREGEAULT, JM ;
THOUVENOT, R ;
CHAUVEAU, F ;
HUET, C ;
LEDON, H .
INORGANIC CHEMISTRY, 1991, 30 (23) :4409-4415
[3]   HYDROTALCITE-PROMOTED EPOXIDATION OF ELECTRON-DEFICIENT ALKENES WITH HYDROGEN-PEROXIDE [J].
CATIVIELA, C ;
FIGUERAS, F ;
FRAILE, JM ;
GARCIA, JI ;
MAYORAL, JA .
TETRAHEDRON LETTERS, 1995, 36 (23) :4125-4128
[4]   HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].
Cavani, F. ;
Trifiro, F. ;
Vaccari, A. .
CATALYSIS TODAY, 1991, 11 (02) :173-301
[5]  
CONNOR JA, 1964, ADV INORG CHEM, V6, P279
[6]   MECHANISM AND DYNAMICS IN THE H-3[PW12O40]-CATALYZED SELECTIVE EPOXIDATION OF TERMINAL OLEFINS BY H2O2 - FORMATION, REACTIVITY, AND STABILITY OF (PO4[WO(O-2)(2)](4))(3-) [J].
DUNCAN, DC ;
CHAMBERS, RC ;
HECHT, E ;
HILL, CL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (02) :681-691
[7]  
Frimer AA., 1985, SINGLET OXYGEN
[8]   A NOVEL HEXANUCLEAR HETEROPOLYPEROXO OXIDATION CATALYST - PREPARATION, X-RAY CRYSTAL-STRUCTURE AND REACTIONS OF [NME(4)](3)[(MEPO(3))(MEPO(2)(OH))W6O13(O-2)(4)(OH)(2)(OH)(2)]CENTER-DOT-4H(2)O [J].
GRIFFITH, WP ;
PARKIN, BC ;
WHITE, AJP ;
WILLIAMS, DJ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (21) :2183-2184
[9]   SYNTHESES OF HYDROTALCITE-LIKE COMPOUNDS AND THEIR STRUCTURES AND PHYSICOCHEMICAL PROPERTIES .1. SYSTEMS MG2+-AL3+-NO-3,MG2+-AL3+-CL-,MG2+-AL3+-CLO-4,NI2P-AL3+-CL- AND ZN2+-AL3+-CL- [J].
MIYATA, S .
CLAYS AND CLAY MINERALS, 1975, 23 (05) :369-&
[10]   EPOXIDATION OF ISOLATED DOUBLE-BONDS WITH 30-PERCENT HYDROGEN-PEROXIDE CATALYZED BY PERTUNGSTATE SALTS [J].
PRANDI, J ;
KAGAN, HB ;
MIMOUN, H .
TETRAHEDRON LETTERS, 1986, 27 (23) :2617-2620