Plasmachemical amine functionalization of porous polystyrene beads: The importance of pore architecture

被引:27
作者
Oye, G
Roucoules, V
Cameron, AA
Oates, LJ
Cameron, NR
Steel, PG
Badayal, JPS [1 ]
Davis, BG
Coe, D
Cox, R
机构
[1] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England
[2] Univ Oxford, Dyson Perrins Lab, Dept Chem, Oxford OX1 3QY, England
[3] GlaxoSmithKline, Med Res Ctr, Stevenage SG1 2NY, Herts, England
基金
英国生物技术与生命科学研究理事会;
关键词
D O I
10.1021/la0202935
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The functionalization of different types of porous polystyrene microspheres using allylamine plasmas has been explored using a combination of Fmoc derivatization chemistry and cross-sectional Raman microscopy. Higher amine group loadings are obtained for small particles with large internal pore diameters.
引用
收藏
页码:8996 / 8999
页数:4
相关论文
共 22 条
[1]   THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].
BARRETT, EP ;
JOYNER, LG ;
HALENDA, PP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380
[2]  
Beck A J., 1998, Plasmas and Polymers, V3, P97
[3]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[4]   Synthesis and evaluation of a scintillant-containing solid support for use in combinatorial chemistry [J].
Clapham, B ;
Sutherland, AJ .
TETRAHEDRON LETTERS, 2000, 41 (13) :2253-2256
[5]  
Denes F, 1997, TRENDS POLYM SCI, V5, P23
[6]   A new solid-phase support for oligonucleotide synthesis [J].
Devivar, RV ;
Koontz, SL ;
Peltier, WJ ;
Pearson, JE ;
Guillory, TA ;
Fabricant, JD .
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 1999, 9 (09) :1239-1242
[7]  
DORWALD FZ, ORGANIC SYNTHESIS SO, P254
[8]   New cation-exchange resins with high reversed-phase character for solid-phase extraction of phenols [J].
Eder, K ;
Buchmeiser, MR ;
Bonn, GK .
JOURNAL OF CHROMATOGRAPHY A, 1998, 810 (1-2) :43-52
[9]  
Früchtel JS, 2000, BIOTECHNOL BIOENG, V71, P94, DOI 10.1002/1097-0290(200021)71:2<94::AID-BIT3>3.0.CO
[10]  
2-Y