Ruthenium-based metathesis initiators: Development and use in ring-opening metathesis polymerization

被引:149
作者
Frenzel, U [1 ]
Nuyken, O [1 ]
机构
[1] Tech Univ Munich, Lehstuhl Makromol Stoffe, D-85748 Garching, Germany
关键词
metathesis; ROMP; catalysis; polymerization; ring-opening polymerization; ruthenium;
D O I
10.1002/pola.10324
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
For many years, olefin metathesis has been a central topic of industrial and academic research because of its great synthetic utility. The, employed initiators cover a wide range of compounds, from simple transition-metal salts to highly sophisticated and well-defined alkylidene complexes. Currently, ruthenium-based catalysts are at the center of attention because of their remarkable tolerance toward oxygen, moisture, and numerous functionalities. This article focuses on recent developments in the field of ring-opening metathesis polymerization using ruthenium-based catalysts. ruthenium-based initiators and their applications to the preparation of advanced polymeric materials are briefly reviewed. (C) 2002 Wiley Pedodicals, Inc.
引用
收藏
页码:2895 / 2916
页数:22
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