Graphene improving lithium-ion battery performance by construction of NiCo2O4/graphene hybrid nanosheet arrays

被引：184

作者：

Chen, Yuejiao ^{[1
]}

Zhu, Jian ^{[1
]}

Qu, Baihua ^{[1
]}

Lu, Bingan ^{[1
]}

Xu, Zhi ^{[1
]}

机构：

[1] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Key Lab Micronano Optoelect Devices, Minist Educ, Changsha 410082, Hunan, Peoples R China

来源：

NANO ENERGY | 2014年 / 3卷

基金：

中国国家自然科学基金;

关键词：

Graphene hybrid arrays; Lithium-ion battery; Pulverization; Cycling stability; ELECTROCHEMICAL PERFORMANCE; ANODE MATERIAL; REVERSIBLE CAPACITY; NANOWIRE ARRAYS; STORAGE; OXIDE; SUPERCAPACITORS; NANOPARTICLES; MICROSPHERES; CAPABILITY;

D O I：

10.1016/j.nanoen.2013.10.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

NiCo2O4 is a potential lithium-ion battery (LIB) anode material that can be applied to the industrial production for commercial applications. However, the capacity and cycling stability of the LIB based on NiCo2O4 should be improved first. Herein, graphene-based NiCo2O4 nanosheet arrays directly grown on nickel foam have been successfully synthesized. This composites array shows significantly improved lithium storage properties with higher reversible capacity and better cycling stability than NiCo2O4 nanosheets. The three-dimensional graphene not only serves as a conductive network to increase the conductivity of the NiCo2O4, but also can offer effective buffering to accommodate the lithiation-induced stress which is beneficial to lithium storage and cycling stability.(C) 2013 Published by Elsevier Ltd.

引用

页码：88 / 94

页数：7

共 40 条

[1] Self-Assembly and Embedding of Nanoparticles by In Situ Reduced Graphene for Preparation of a 3D Graphene/Nanoparticle Aerogel [J].

Chen, Wufeng ;

Li, Sirong ;

Chen, Chunhua ;

Yan, Lifeng .

ADVANCED MATERIALS, 2011, 23 (47) :5679-+

[2] Gram-scale synthesis of ultrasmall SnO2 nanocrystals with an excellent electrochemical performance [J].

Chen, Yuejiao ;

Ma, Jianmin ;

Li, Qiuhong ;

Wang, Taihong .

NANOSCALE, 2013, 5 (08) :3262-3265

[3] Synthesis of ZnSnO3 mesocrystals from regular cube-like to sheet-like structures and their comparative electrochemical properties in Li-ion batteries [J].

Chen, Yuejiao ;

Qu, Baihua ;

Mei, Lin ;

Lei, Danni ;

Chen, Libao ;

Li, Qiuhong ;

Wang, Taihong .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (48) :25373-25379

[4] Core-ring structured NiCo2O4 nanoplatelets:: Synthesis, characterization, and electrocatalytic applications [J].

Cui, Bai ;

Lin, Hong ;

Li, Jian-Bao ;

Li, Xin ;

Yang, Jun ;

Tao, Jie .

ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (09) :1440-1447

[5] Copper Ferrite-Graphene Hybrid: A Multifunctional Heteroarchitecture for Photocatalysis and Energy Storage [J].

Fu, Yongsheng ;

Chen, Qun ;

He, Mingyang ;

Wan, Yunhai ;

Sun, Xiaoqiang ;

Xia, Hui ;

Wang, Xin .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (36) :11700-11709

[6] Self-assembled nanowire-nanoribbon junction arrays of ZnO [J].

Gao, PX ;

Wang, ZL .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (49) :12653-12658

[7] Hybrid structure of cobalt monoxide nanowire @ nickel hydroxidenitrate nanoflake aligned on nickel foam for high-rate supercapacitor [J].

Guan, Cao ;

Liu, Jinping ;

Cheng, Chuanwei ;

Li, Hongxing ;

Li, Xianglin ;

Zhou, Weiwei ;

Zhang, Hua ;

Fan, Hong Jin .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (11) :4496-4499

[8] Interdispersed Amorphous MnOx-Carbon Nanocomposites with Superior Electrochemical Performance as Lithium-Storage Material [J].

Guo, Juchen ;

Liu, Qing ;

Wang, Chunsheng ;

Zachariah, Michael R. .

ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (04) :803-811

[9] An Integrated Power Pack of Dye-Sensitized Solar Cell and Li Battery Based on Double-Sided TiO2 Nanotube Arrays [J].

Guo, Wenxi ;

Xue, Xinyu ;

Wang, Sihong ;

Lin, Changjian ;

Wang, Zhong Lin .

NANO LETTERS, 2012, 12 (05) :2520-2523

[10] Rectangular Bunched Rutile TiO2 Nanorod Arrays Grown on Carbon Fiber for Dye-Sensitized Solar Cells [J].

Guo, Wenxi ;

Xu, Chen ;

Wang, Xue ;

Wang, Sihong ;

Pan, Caofeng ;

Lin, Changjian ;

Wang, Zhong Lin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (09) :4437-4441

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