Supramolecular ABC Triblock Copolymers

被引：107

作者：

Ambade, Ashootosh V. ^{[1
,2
]}

Yang, Si Kyung ^{[1
,2
]}

Weck, Marcus ^{[1
,2
]}

机构：

[1] NYU, Dept Chem, New York, NY 10003 USA

[2] NYU, Inst Mol Design, New York, NY 10003 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 16期

基金：

美国国家科学基金会;

关键词：

block copolymers; receptors; ring opening polymerization; ruthenium; supramolecular chemistry; OPENING METATHESIS POLYMERIZATION; TRANSFER RADICAL POLYMERIZATION; PSEUDO-BLOCK-COPOLYMERS; MAIN-CHAIN; MOLECULAR RECOGNITION; LIGAND INTERACTIONS; DIBLOCK COPOLYMERS; TUNABLE PROPERTIES; MODULAR APPROACH; CLICK CHEMISTRY;

D O I：

10.1002/anie.200805116

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Just add it! Ruthenium initiators functionalized with hydrogen-bonding sites were utilized in ringopening metathesis polymerization to prepare heterotelechelic polymers with hydrogen-bonding and metal-coordination units in a single step. Supramolecular ABC triblock copolymers were then self-assembled in one pot by simply adding complementary telechelic polymers to a solution of the heterotelechelic polymer (see picture). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2894 / 2898

页数：5

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