Development of a new automated speciation analyser - result of an international interdisciplinary co-operation between scientific and industrial partners

被引:6
作者
Feldhaus, R
Buscher, W
Kleine-Benne, E
Quevauviller, P
机构
[1] Inst Chemo & Biosensor, D-48149 Munster, Germany
[2] Gerstel GmbH & Co KG, D-45473 Mulheim, Germany
[3] Commiss European Communities, B-1049 Brussels, Belgium
关键词
analyser; automation; interdisciplinary; international; monitoring; trace element;
D O I
10.1016/S0165-9936(02)00504-6
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The importance of monitoring trace-element species is increasingly recognised. Such methods are needed for risk assessment of many potentially hazardous substances, such as methylmercury and tributyltin, for example for environmental or food control, medicine or workplace monitoring. Atomic spectro-metric techniques alone are incapable of determining elemental species directly, because the relevant information about oxidation or metal-binding state is lost in the atomisation step. As a result, these methods must be combined with separation techniques in order to obtain methods that are highly sensitive as well as species selective. To develop new analytical methods and procedures for element speciation interdisciplinary research is essential. Accordingly, an international interdisciplinary consortium was formed to develop the new automated speciation analyser (ASA). Analytical chemists and physicists from several European institutes and two industrial companies co-operated in this project. As a result, the continuous exchange of scientific results and practical experience, combined with consideration of the needs of routine analytical laboratories, led to the development of an industrial prototype for trace-element speciation. (C) 2002 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码:356 / 365
页数:10
相关论文
共 21 条
[1]   Exploration of a multicapillary column for use in elevated speed gas chromatography [J].
Baumbach, JI ;
Eiceman, GA ;
Klockow, D ;
Sielemann, S ;
von Irmer, A .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 1997, 66 (04) :225-239
[2]   EVALUATION OF A MICROWAVE-INDUCED PLASMA IN HELIUM AT ATMOSPHERIC-PRESSURE AS AN ELEMENT-SELECTIVE DETECTOR FOR GAS-CHROMATOGRAPHY [J].
BEENAKKER, CIM .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1977, 32 (3-4) :173-187
[3]  
BROEKAERT JAC, 1990, NATO ASI SERIES G, V23
[4]  
CAMMANN K, 1988, J ANAL CHEM+, V337, P336
[5]   Lead speciation in rainwater samples by modified fused silica capillaries coupled to a direct injection nebulizer (DIN) for sample introduction in ICP-MS [J].
Garcia-Sanchez, R ;
Feldhaus, R ;
Bettmer, J ;
Ebdon, L .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2001, 16 (09) :1028-1034
[6]  
Harrison R. M., 1989, ENV ANAL USING CHROM
[7]   COMPARISON OF DISTILLATION WITH OTHER CURRENT ISOLATION METHODS FOR THE DETERMINATION OF METHYL MERCURY-COMPOUNDS IN LOW-LEVEL ENVIRONMENTAL-SAMPLES .2. WATER [J].
HORVAT, M ;
LIANG, L ;
BLOOM, NS .
ANALYTICA CHIMICA ACTA, 1993, 282 (01) :153-168
[8]   Lessons from Minamata mercury pollution, Japan - After a continuous 22 years of observation [J].
Kudo, A ;
Fujikawa, Y ;
Miyahara, S ;
Zheng, J ;
Takigami, H ;
Sugahara, M ;
Muramatsu, T .
WATER SCIENCE AND TECHNOLOGY, 1998, 38 (07) :187-193
[9]   Gas chromatography-inductively coupled plasma time-of-flight mass spectrometry for the speciation analysis of organometallic compounds [J].
Leach, AM ;
Heisterkamp, M ;
Adams, FC ;
Hieftje, GM .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2000, 15 (02) :151-155
[10]   The determination of mercury species in environmental and biological samples (Technical report) [J].
Morita, M ;
Yoshinaga, J ;
Edmonds, JS .
PURE AND APPLIED CHEMISTRY, 1998, 70 (08) :1585-1615