Metal Organic Frameworks for Natural Gas Storage in Vehicles

被引：19

作者：

Arnold, Lena ^{[1
]}

Averlant, Gauthier ^{[1
]}

Marx, Stefan ^{[1
]}

Weickert, Mathias ^{[1
]}

Mueller, Ulrich ^{[1
]}

Mertel, Jonathan ^{[2
,3
]}

Horch, Carsten ^{[3
]}

Peksa, Mikulas ^{[3
]}

Stallmach, Frank ^{[3
]}

机构：

[1] BASF SE, D-67056 Ludwigshafen, Germany

[2] Wilhelm Ostwald Schule Leipzig, D-04279 Leipzig, Germany

[3] Univ Leipzig, Inst Expt Phys 1, D-04103 Leipzig, Germany

来源：

CHEMIE INGENIEUR TECHNIK | 2013年 / 85卷 / 11期

关键词：

Diffusion; Metal organic framework; Natural gas storage; Natural gas vehicle; SELF-DIFFUSION; MOLECULAR SIMULATIONS; NEUTRON-SCATTERING; CARBON-DIOXIDE; POROUS-MEDIA; ADSORPTION; NMR; DYNAMICS; METHANE; MIL-47;

D O I：

10.1002/cite.201300093

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

With the increasing demand for alternative fuels the storage of natural gas (NG) in adsorbents like metal organic frameworks (MOFs) will become more important. In order to use MOFs as storage media in fuel delivery systems, the optimization of mass and energy transfer of the system is crucial. For rapid NG filling of a tank, molecules need to reach the adsorption sites within a reasonable time while the heat of adsorption should be dissipated to the environment. In this article, mass transfer in shaped bodies of MOFs was determined by permeability measurements and pulsed field gradient (PFG) NMR spectroscopy. The heat dissipation was also experimentally measured and both data sets were used to set up a theoretical density function theory model to predict the behavior of MOFs for NG storage.

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页码：1726 / 1733

页数：8

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