A short history of ionic liquids - from molten salts to neoteric solvents

被引：1497

作者：

Wilkes, JS ^{[1
]}

机构：

[1] USAF Acad, Chem Res Ctr, Colorado Springs, CO 80840 USA

来源：

GREEN CHEMISTRY | 2002年 / 4卷 / 02期

关键词：

D O I：

10.1039/b110838g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionic liquids, defined here as salts with melting temperatures below 100degreesC, evolved from traditional high temperature molten salts. Some materials we would now recognize as ionic liquids were observed as far back as the mid 19th century. The quest for useful molten salts with lower melting temperatures led to inorganic chloroaluminates, to organic chloroaluminates, then to the water and air stable salts now being developed for green chemistry applications.

引用

页码：73 / 80

页数：8

共 37 条

[1] ADAMS RT, 1967, Patent No. 3347947
[2] [Anonymous], 1976, ADV CHEM SERIES
[3] Carlin RT, 1996, J APPL ELECTROCHEM, V26, P1147
[4] CARLIN RT, 1994, CHEM NONAQUEOUS SOLU, P277
[5] *CAS, 78041073 CAS
[6] CEAUSESCU E, 1988, PLASTE KAUTSCH, V35, P378
[7] Copeland JL, 1974, Transport Properties in Ionic Liquids
[8] DECKER MM, 1987, BRLTR2864 ARM BALL R
[9] PROPERTIES OF 1,3-DIALKYLIMIDAZOLIUM CHLORIDE ALUMINUM-CHLORIDE IONIC LIQUIDS .2. PHASE-TRANSITIONS, DENSITIES, ELECTRICAL CONDUCTIVITIES, AND VISCOSITIES
FANNIN, AA
FLOREANI, DA
KING, LA
LANDERS, JS
PIERSMA, BJ
STECH, DJ
VAUGHN, RL
WILKES, JS
WILLIAMS, JL
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (12) : 2614 - 2621
[10] STRUCTURAL AND ELECTROCHEMICAL CHARACTERIZATION OF 1,3-BIS-(4-METHYLPHENYL)IMIDAZOLIUM CHLORIDE
FULLER, J
CARLIN, RT
[J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1994, 24 (08) : 489 - 493

← 1 2 3 4 →