Efficiency limits for single junction and tandem solar cells

被引:296
作者
Meillaud, F. [1 ]
Shah, A. [1 ]
Droz, C. [1 ]
Vallat-Sauvain, E. [1 ]
Miazza, C. [1 ]
机构
[1] Univ Neuchatel, Inst Microtechnol, CH-2000 Neuchatel, Switzerland
关键词
amorphous and microcrystalline silicon; single p-n and p-i-n junction solar cells; tandem solar cells; efficiency limits;
D O I
10.1016/j.solmat.2006.06.002
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Basic limitations of single-junction and tandem p-n and p-i-n diodes are established from thermodynamical considerations on radiative recombination and semi-empirical considerations on the classical diode equations. These limits are compared to actual values of short-circuit current open-circuit voltage, fill factor and efficiency for amorphous (a-Si:H) and microcrystalline (mu c-Si:H) silicon solar cells. For single-junction cells, major efficiency gains should be achievable by increasing the short-circuit current density by better light trapping. The limitations of p-i-n junctions are estimated from recombination effects in the intrinsic layer. The efficiency of double-junction cells is presented as a function of the energy gap of top and bottom cells, confirming the 'micromorph' tandem (a-Si:H/mu c-Si:H) as an optimum combination of tandem solar cells. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:2952 / 2959
页数:8
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