Metal-Containing Carbon Nitride Compounds: A New Functional Organic-Metal Hybrid Material

被引:1211
作者
Wang, Xinchen [1 ,2 ]
Chen, Xiufang [1 ]
Thomas, Arne [2 ]
Fu, Xianzhi [1 ]
Antonietti, Markus [2 ]
机构
[1] Fuzhou Univ, State Key Lab Breeding Base Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
[2] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14476 Potsdam, Germany
关键词
VISIBLE-LIGHT; IRON; EPOXIDATION; CYTOCHROME-P450; HYDROXYLATION; DEGRADATION; IRRADIATION; POLLUTANTS; COMPLEXES; OXIDATION;
D O I
10.1002/adma.200802627
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electronic and optical functions of polymeric C3N4 can be easily modified by the inclusion of metal species such as Fe in its structure. The metal species lowers the bandgap and expands the light absorption of the material further into the visible region of the electromagnetic spectrum, while keeping a sufficient overpotential for carrying out oxidation reactions.
引用
收藏
页码:1609 / +
页数:5
相关论文
共 36 条
  • [1] [Anonymous], 1992, Handbook of X-Ray Photoelectron Spectroscopy: A Reference Book of Standard Spectra for Identification and Interpretation of XPS Data 1992
  • [2] Catalytic epoxidation and 1,2-dihydroxylation of olefins with bispidine-iron(II)/H2O2 systems
    Bukowski, Michael R.
    Comba, Peter
    Lienke, Achim
    Limberg, Christian
    de Laorden, Carlos Lopez
    Mas-Balleste, Ruben
    Merz, Michael
    Que, Lawrence, Jr.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (21) : 3446 - 3449
  • [3] A predictably selective aliphatic C-H oxidation reaction for complex molecule synthesis
    Chen, Mark S.
    White, M. Christina
    [J]. SCIENCE, 2007, 318 (5851) : 783 - 787
  • [4] REDUCTION OF OXIDES OF IRON, COBALT, TITANIUM AND NIOBIUM BY LOW-ENERGY ION-BOMBARDMENT
    CHOUDHURY, T
    SAIED, SO
    SULLIVAN, JL
    ABBOT, AM
    [J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1989, 22 (08) : 1185 - 1195
  • [5] Costas M, 2002, ANGEW CHEM INT EDIT, V41, P2179, DOI 10.1002/1521-3773(20020617)41:12<2179::AID-ANIE2179>3.0.CO
  • [6] 2-F
  • [7] Electronic and structural properties of two-dimensional carbon nitride graphenes
    Deifallah, Malek
    McMillan, Paul F.
    Cora, Furio
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (14) : 5447 - 5453
  • [8] Metal-free activation CO2 by mesoporous graphitic carbon nitride
    Goettmann, Frederic
    Thomas, Arne
    Antonietti, Markus
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (15) : 2717 - 2720
  • [9] Chemical synthesis of mesoporous carbon nitrides using hard templates and their use as a metal-free catalyst for friedel-crafts reaction of benzene
    Goettmann, Frederic
    Fischer, Anna
    Antonietti, Markus
    Thomas, Arne
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (27) : 4467 - 4471
  • [10] Synthesis of g-C3N4 nanoparticles in mesoporous silica host matrices
    Groenewolt, M
    Antonietti, M
    [J]. ADVANCED MATERIALS, 2005, 17 (14) : 1789 - +