Isolation and spectroscopic characterisation of C60F18CF2, the first difluoromethano[60]fullerene

被引：16

作者：

Avent, AG ^{[1
]}

Boltalina, OV

Lukonin, AY

Street, JM

Taylor, R

机构：

[1] Univ Sussex, CPES Sch, Chem Lab, Brighton BN1 9QJ, E Sussex, England

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[3] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2000年 / 01期

关键词：

D O I：

10.1039/a909157b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

From the fluorination of [60]fullerene by K2PtF6 at 465 degrees C under 0.1 bar, we have isolated and characterised C60F18CF2 which has C-s symmetry and is isostructural with C60F18O; it co-elutes (HPLC) with a minor unsymmetrical isomer.

引用

页码：1 / 3

页数：3

共 15 条

[1] C60F18O:: Isolation, spectroscopic characterisation and structural calculations [J].

Avent, AG ;

Boltalina, OV ;

Fowler, PW ;

Lukonin, AY ;

Pavlovich, VK ;

Sandall, JPB ;

Street, JM ;

Taylor, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1998, (06) :1319-1322

[2] Synthesis and characterisation of the methanofullerenes, C-60(CHCN) and C-60(CBr2) [J].

Benito, AM ;

Darwish, AD ;

Kroto, HW ;

Meidine, MF ;

Taylor, R ;

Walton, DRM .

TETRAHEDRON LETTERS, 1996, 37 (07) :1085-1086

[3] The 3He NMR spectra of C60F18 and C60F36;: the parallel between hydrogenation and fluorination [J].

Boltalina, OV ;

Bühl, M ;

Khong, A ;

Saunders, M ;

Street, JM ;

Taylor, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1999, (07) :1475-1479

[4] Preparation and characterisation of C60F18 [J].

Boltalina, OV ;

Markov, VY ;

Taylor, R ;

Waugh, MP .

CHEMICAL COMMUNICATIONS, 1996, (22) :2549-2550

[5] HYPERFLUORINATION OF [60]FULLERENE BY KRYPTON DIFLUORIDE [J].

BOLTALINA, OV ;

ABDULSADA, AK ;

TAYLOR, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1995, (05) :981-985

[6]

EMSLEY JW, 1971, PROGR NMR SPECTROSCO, V7

[7] SYNTHESIS AND MASS-SPECTRAL ANALYSIS OF C-60-DIHALOCARBENE ADDUCTS [J].

ISHIDA, T ;

FURUDATE, T ;

NOGAMI, T ;

KUBOTA, M ;

HIRANO, T ;

OHASHI, M .

FULLERENE SCIENCE AND TECHNOLOGY, 1995, 3 (04) :399-409

[8] SPECTRAL CHARACTERIZATION OF ANTHRACENE-C60, CYCLOPENTADIENE-C60, AND DICHLOROCARBENE-C60 ADDUCTS [J].

ISHIDA, T ;

TSUDA, M ;

NOGAMI, T ;

KURONO, S ;

OHASHI, M .

FULLERENE SCIENCE AND TECHNOLOGY, 1994, 2 (02) :155-164

[9]

Komatsu K., 1993, FULLERENE SCI TECHN, V1, P231

[10] C61Br2: A new synthesis of dibromomethanofullerene and mass spectrometric evidence of the carbon allotropes C-121 and C-122 [J].

Osterodt, J ;

Vogtle, F .

CHEMICAL COMMUNICATIONS, 1996, (04) :547-548

← 1 2 →