Efficient Regeneration of Partially Spent Ammonia Borane Fuel

被引：220

作者：

Davis, Benjamin L. ^{[2
]}

Dixon, David A. ^{[1
]}

Garner, Edward B. ^{[1
]}

Gordon, John C. ^{[2
]}

Matus, Myrna H. ^{[1
]}

Scott, Brian ^{[2
]}

Stephens, Frances H. ^{[2
]}

机构：

[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

[2] Los Alamos Natl Lab Lab, Div Chem, Los Alamos, NM 87545 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 37期

关键词：

amine-boranes; density functional calculations; hydrogen storage; NMR spectroscopy; sustainable chemistry; CHEMICAL HYDROGEN STORAGE; CATALYZED DEHYDROGENATION;

D O I：

10.1002/anie.200900680

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Going full circle: Ammonia borane is a potential H2- releasing fuel. Polyborazylene, a form of the spent fuel, can be regenerated efficiently in a one-pot process by the stepwise addition of appropriate digesting and reducing agents. A unique feature of this process is the formation of NH 3, which is retained by some of the digested species. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6812 / 6816

页数：5

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