Semiconductive polymer blends: Correlating structure with transport properties at the nanoscale

被引:148
作者
Ionescu-Zanetti, C
Mechler, A
Carter, SA
Lal, R [1 ]
机构
[1] Univ Calif Santa Barbara, Neurosci Res Inst, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Cruz, Dept Phys, Santa Cruz, CA 95064 USA
关键词
D O I
10.1002/adma.200305747
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Multimodal atomic force microscopy (AFM) was used to map charge transfer properties in correlation to the molecular superstructure of poly(ethyldioxythiophene)-poly(styrenesulfonic acid) (see Figure). The lamellar domains of the polymer blend are indicated by phase shifts. Efficient charge injection occurs when lamellar edges of the superstructure are exposed to a conductive AFM probe. Efficiency of charge injection at polymer-electrode interfaces could be enhanced by controlling lamellar orientation.
引用
收藏
页码:385 / +
页数:6
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