Structural characterization and catalytic activity of the rhodium-carbene complex Rh(PPh3)2(IMes)Cl (IMes = bis(1,3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)

被引：77

作者：

Grasa, GA

Moore, Z

Martin, KL

Stevens, ED

Nolan, SP

Paquet, V

Lebel, H ^{[1
]}

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

[2] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 658卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会; 美国国家科学基金会;

关键词：

structural characterization; catalytic activity; rhodium-carbene complexes;

D O I：

10.1016/S0022-328X(02)01638-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The rhodium-carbene complex Rh(PPh3)(2)(IMes)Cl (2) is an active catalyst for the hydroboration of simple olefins at room temperature. The reactivity of 2 was also tested in the methylenation of aldehydes. The crystal structure of 2 is also reported (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：126 / 131

页数：6

共 56 条

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