Chemoenzymatic routes to chiral (non-racemic) cyclopropanes. Preparation of a key intermediate for the synthesis of (1R)-cis-pyrethroids

被引：14

作者：

Banwell, MG

Forman, GS

机构：

[1] Research School of Chemistry, Institute of Advanced Studies, Australian National University, Canberra

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 21期

关键词：

ENANTIOSELECTIVE SYNTHESIS;

D O I：

10.1039/p19960002565

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The microbial oxidation product 2 (X = Br) has been converted into the chiral (non-racemic) cyclopropane II, a synthon for the commercially significant (1R)-cis-pyrethroid class of insecticides.

引用

页码：2565 / 2566

页数：2