High-Nuclearity Silver Clusters Templated by Carbonates Generated from Atmospheric Carbon Dioxide Fixation

被引：158

作者：

Bian, Shu-Dan ^{[1
]}

Jia, Jian-Hua ^{[1
]}

Wang, Quan-Ming ^{[1
]}

机构：

[1] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 10期

关键词：

CO2; FIXATION; COORDINATION; COMPLEXES; COPPER(II); CHEMISTRY; SALTS;

D O I：

10.1021/ja8087696

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two high-nuclearity silver clusters have been prepared by reacting AgC2But with AgBF4 (or AgOTf) in the presence of TMEDA in air. The reaction takes up atmospheric CO2 to give CO32-, which functions as a template for the formation of the cage compounds, whose nuclearities depend on the particular counteranions employed

引用

页码：3422 / +

页数：3

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