Catalysis for Society: Towards Improved Process Efficiency in Catalytic Selective Oxidations

被引：43

作者：

Cavani, Fabrizio ^{[1
]}

Ballarini, Nicola ^{[1
]}

Luciani, Silvia ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim Ind & Mat, I-40136 Bologna, Italy

来源：

TOPICS IN CATALYSIS | 2009年 / 52卷 / 08期

关键词：

Selective oxidation; Sustainability; Oxidation of o-xylene; Oxidative desulphurisation; Cyclic redox process; GAS-PHASE EPOXIDATION; OXIDE-BASED CATALYSTS; O-XYLENE; NITROUS-OXIDE; V/TI/O CATALYSTS; HETEROGENEOUS CATALYSTS; PHTHALIC-ANHYDRIDE; MIXED OXIDES; METAL-OXIDE; DEHYDROGENATION;

D O I：

10.1007/s11244-009-9244-y

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This short review documents some examples of the recent innovations in the field of catalytic selective oxidation aimed at improving process performance and process sustainability in general. Some strategies adopted in order to increase selectivity to the desired product are illustrated, including unconventional procedures for the oxidation reaction-the cyclic mode as compared to the co-feed mode-and special arrangements of the catalytic bed, as in the case of the oxidation of o-xylene to phthalic anhydride. The choice of which oxidant to use is also discussed, in relation to the process of oxidative desulphurization of gasoil.

引用

页码：935 / 947

页数：13

共 93 条

[31] Mode of arrangement of components in mixed vanadia catalyst and its bearing for oxidation catalysis [J].