Aerobic oxidation of cyclohexane catalyzed by Fe(III)(5,10,15,20-tetrakis(pentafluorophenyl)porphyrin)Cl in sub- and super-critical CO2

被引：49

作者：

Wu, XW ^{[1
]}

Oshima, Y ^{[1
]}

Koda, S ^{[1
]}

机构：

[1] UNIV TOKYO, SCH ENGN, DEPT CHEM SYST ENGN, BUNKYO KU, TOKYO 113, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 10期

关键词：

D O I：

10.1246/cl.1997.1045

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aerobic oxidation of cyclohexane to yield cyclohexanol and cyclohexanone in the presence of a Fe-porphyrin catalyst bearing meso-pentafluorophenyl group and acetaldehyde has been efficiently enhanced in pressurized CO2. The reaction rate takes a maximum value in the neighborhood of critical pressure.

引用

页码：1045 / 1046

页数：2

共 9 条

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