Pd/C-catalyzed transfer reduction of aryl chlorides with sodium formate in water

被引：37

作者：

Arcadi, A

Cerichelli, G

Chiarini, M

Vico, R

Zorzan, D

机构：

[1] Univ Aquila, Dipartimento Chim Ingn Chim & Mat, I-67010 Coppito, AQ, Italy

[2] Univ Teramo, Dipartimento Sci Alimenti, I-64023 Mosciano Stn, TE, Italy

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 2004卷 / 16期

关键词：

reductive dechlorination; palladium; catalysis; sodium formate; aryl chlorides;

D O I：

10.1002/ejoc.200400258

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sodium formate catalytic transfer reduction, in the presence of palladium on carbon, accomplishes not only the rapid dehalogenation of aromatic chlorocarbons in water at room temperature, but also the reduction of the aromatic moieties to alicyclic rings at 100degreesC. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

引用

收藏

页码：3404 / 3407

页数：4

相关论文

共 46 条

[11] PdCl2-catalyzed reduction of organic halides by triethylsilane [J].

Boukherroub, R ;

Chatgilialoglu, C ;

Manuel, G .

ORGANOMETALLICS, 1996, 15 (05) :1508-1510

[12]

BURDESKA K, 1982, SYNTHESIS-STUTTGART, P940

[13] Palladium-catalyzed hydroxycarbonylation of aryl and vinyl halides or triflates by acetic anhydride and formate anions [J].

Cacchi, S ;

Fabrizi, G ;

Goggiamani, A .

ORGANIC LETTERS, 2003, 5 (23) :4269-4272

[14] Hydrodechlorination of 1,2,4-trichlorobenzene on nickel-based catalysts prepared from several Ni/Mg/Al hydrotalcite-like precursors [J].

Cesteros, Y ;

Salagre, P ;

Medina, F ;

Sueiras, JE ;

Tichit, D ;

Coq, B .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2001, 32 (1-2) :25-35

[15] Nickel(0)/imidazolium chloride catalyzed reduction of aryl halides [J].

Desmarets, C ;

Kuhl, S ;

Schneider, R ;

Fort, Y .

ORGANOMETALLICS, 2002, 21 (08) :1554-1559

[16] Dehalogenation of polychloroarenes with HSiEt3 catalyzed by an homogeneous rhodium-triphenylphosphine system [J].

Esteruelas, MA ;

Herrero, J ;

López, FM ;

Martín, M ;

Oro, LA .

ORGANOMETALLICS, 1999, 18 (06) :1110-1112

[17] Exhaustive hydrodechlorination of chlorinated aromatic environmental pollutants to alicyclic compounds [J].

Ghattas, A ;

Abu-Reziq, R ;

Avnir, D ;

Blum, J .

GREEN CHEMISTRY, 2003, 5 (01) :40-43

[18] Hydrodechlorination of chlorobenzene on Nb2O5-supported Pd catalysts influence of microwave irradiation during preparation on the stability of the catalyst [J].

Gopinath, R ;

Rao, KN ;

Prasad, PSS ;

Madhavendra, SS ;

Narayanan, S ;

Vivekanandan, G .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 181 (1-2) :215-220

[19] TRANSFORMATIONS OF CHLOROARENES, CATALYZED BY TRANSITION-METAL COMPLEXES [J].

GRUSHIN, VV ;

ALPER, H .

CHEMICAL REVIEWS, 1994, 94 (04) :1047-1062

[20] Catalytic dechlorination of aromatic chlorides using Grignard reagents in the presence of (C5H5)2TiCl2 [J].

Hara, R ;

Sato, K ;

Sun, WH ;

Takahashi, T .

CHEMICAL COMMUNICATIONS, 1999, (09) :845-846

← 1 2 3 4 5 →