Structural and spectral studies of di-2-pyridyl ketone 3-piperidyl- and 3-hexamethyleneiminylthiosemicarbazone and their cobalt(II), nickel(II) and copper(II) complexes

被引：28

作者：

Swearingen, JK

Kaminsky, W

West, DX ^{[1
]}

机构：

[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA

[2] Illinois State Univ, Dept Chem, Normal, IL 61790 USA

来源：

TRANSITION METAL CHEMISTRY | 2002年 / 27卷 / 07期

关键词：

D O I：

10.1023/A:1020311408821

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cobalt(II), nickel(II) and copper(II) complexes of di-2-pyridyl ketone 3-piperidyl- and 3-hexamethyleneiminylthiosemicarbazones (HDPypip and HDPyhexim, respectively) have been prepared and characterized by physical and spectral methods. Use of 1: 2 thiosemicarbazone-to-metal chloride molar ratios in the preparation of the complexes has produced both mononuclear and polynuclear species for the three metal ions. Crystal structures of the HDPypip, HDPyhexim and [Ni(DPyhexim)Cl] have been determined and aid the assignments of the i.r., n.m.r., u.v. vis. n.i.r. and e.s.r. spectra for the various complexes.

引用

收藏

页码：724 / 731

页数：8

相关论文

共 45 条

[21] METAL-COMPLEXES OF SULFUR-NITROGEN CHELATING-AGENTS .5. 2-N-ETHYLAMINOCYCLOPENTENE-1-DITHIOCARBOXYLIC ACID COMPLEXES OF NI(II), PD(II), PT(II), CO(II), CO(III), AND CU(I) [J].

NAG, K ;

JOARDAR, DS .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1976, 54 (17) :2827-2831

[22] METAL-COMPLEXES OF SULFUR NITROGEN CHELATING-AGENTS .11. SYNTHESIS, CHARACTERIZATION, AND THERMODYNAMICS OF NUCLEOPHILIC-SUBSTITUTION REACTIONS OF MONOHALOGENO NICKEL(II) COMPLEXES OF TRIDENTATE LIGANDS OF THE TYPE SNN IN SOLUTION AND THE SOLID-STATE [J].

ROY, R ;

CHAUDHURY, M ;

MONDAL, SK ;

NAG, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (08) :1681-1686

[23]

SAHA N, 1990, INDIAN J CHEM A, V29, P292

[24] A FACILE SYNTHESIS OF THIOSEMICARBAZIDES AND THIOSEMICARBAZONES BY THE TRANSAMINATION OF 4-METHYL-4-PHENYL-3-THIOSEMICARBAZIDE [J].

SCOVILL, JP .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1991, 60 (1-2) :15-19

[25]

SENGUPTA SK, 1980, ACTA CHIM HUNG, V104, P89

[26]

Sheldrick G.M., 1997, SHELX 97 PROGRAM REF

[27] COMPLEXES OF DIVALENT NICKEL AND COPPER WITH THE SCHIFF-BASE DERIVED FROM 2-(2-AMINOPHENYL)BENZIMIDAZOLE AND BENZALDEHYDE [J].

SOUZA, P ;

GARCIAVAZQUEZ, JA ;

MASAGUER, JR .

TRANSITION METAL CHEMISTRY, 1984, 9 (08) :318-321

[28] Structural and spectral studies of di-2-pyridyl ketone N(4)-methyl- and N(4)-dimethylthiosemicarbazone and their metal complexes [J].

Swearingen, JK ;

West, DX .

TRANSITION METAL CHEMISTRY, 2001, 26 (03) :252-260

[29] Different structures for two very similar 2-benzoylpyridine azacyclothiosemicarbazones [J].

Valdes-Martinez, J ;

Hernandez-Ortega, S ;

West, DX ;

Ives, JS ;

Bain, GA .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1998, 213 (04) :246-248

[30] NEW ANALYTICAL SCATTERING-FACTOR FUNCTIONS FOR FREE ATOMS AND IONS [J].

WAASMAIER, D ;

KIRFEL, A .

ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :416-431

← 1 2 3 4 5 →