Unique Properties of Halide Perovskites as Possible Origins of the Superior Solar Cell Performance

被引：1953

作者：

Yin, Wan-Jian ^{[1
,2
]}

Shi, Tingting ^{[1
,2
]}

Yan, Yanfa ^{[1
,2
]}

机构：

[1] Univ Toledo, Dept Phys & Astron, Toledo, OH 43606 USA

[2] Univ Toledo, Wright Ctr Photovolta Innovat & Commercializat, Toledo, OH 43606 USA

来源：

ADVANCED MATERIALS | 2014年 / 26卷 / 27期

关键词：

LEAD IODIDE PEROVSKITE; EFFICIENT; TRANSPORT; DEFECTS; LENGTHS;

D O I：

10.1002/adma.201306281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Halide perovskite solar cells have the potential to exhibit higher energy conversion efficiencies with ultrathin films than conventional thin-film solar cells based on CdTe, CuInSe2, and Cu2ZnSnSe4. The superior solar-cell performance of halide perovskites may originate from its high optical absorption, comparable electron and hole effective mass, and electrically clean defect properties, including point defects and grain boundaries.

引用

页码：4653 / +

页数：7

共 51 条

[1] Confined and Chemically Flexible Grain Boundaries in Polycrystalline Compound Semiconductors [J].

Abou-Ras, Daniel ;

Schmidt, Sebastian S. ;

Caballero, Raquel ;

Unold, Thomas ;

Schock, Hans-Werner ;

Koch, Christoph T. ;

Schaffer, Bernhard ;

Schaffer, Miroslava ;

Choi, Pyuck-Pa ;

Cojocaru-Miredin, Oana .

ADVANCED ENERGY MATERIALS, 2012, 2 (08) :992-998

[2] Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3) PbI3 for solid-state sensitised solar cell applications [J].

Baikie, Tom ;

Fang, Yanan ;

Kadro, Jeannette M. ;

Schreyer, Martin ;

Wei, Fengxia ;

Mhaisalkar, Subodh G. ;

Graetzel, Michael ;

White, Tim J. .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5628-5641

[3] The Swift Surge of Perovskite Photovoltaics [J].

Bisquert, Juan .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2013, 4 (15) :2597-2598

[4] Ab initio investigation of hybrid organic-inorganic perovskites based on tin halides [J].

Borriello, Ivo ;

Cantele, Giovanni ;

Ninno, Domenico .

PHYSICAL REVIEW B, 2008, 77 (23)

[5] Structural and electronic properties of hybrid perovskites for high-efficiency thin-film photovoltaics from first-principles [J].

Brivio, Federico ;

Walker, Alison B. ;

Walsh, Aron .

APL MATERIALS, 2013, 1 (04)

[6] Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].

Burschka, Julian ;

Pellet, Norman ;

Moon, Soo-Jin ;

Humphry-Baker, Robin ;

Gao, Peng ;

Nazeeruddin, Mohammad K. ;

Graetzel, Michael .

NATURE, 2013, 499 (7458) :316-+

[7] High performance hybrid solar cells sensitized by organolead halide perovskites [J].

Cai, Bing ;

Xing, Yedi ;

Yang, Zhou ;

Zhang, Wen-Hua ;

Qiu, Jieshan .

ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (05) :1480-1485

[8] Classification of Lattice Defects in the Kesterite Cu2ZnSnS4 and Cu2ZnSnSe4 Earth-Abundant Solar Cell Absorbers [J].

Chen, Shiyou ;

Walsh, Aron ;

Gong, Xin-Gao ;

Wei, Su-Huai .

ADVANCED MATERIALS, 2013, 25 (11) :1522-1539

[9] CsSnI3: Semiconductor or Metal? High Electrical Conductivity and Strong Near-Infrared Photoluminescence from a Single Material. High Hole Mobility and Phase-Transitions [J].

Chung, In ;

Song, Jung-Hwan ;

Im, Jino ;

Androulakis, John ;

Malliakas, Christos D. ;

Li, Hao ;

Freeman, Arthur J. ;

Kenney, John T. ;

Kanatzidis, Mercouri G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (20) :8579-8587

[10] All-solid-state dye-sensitized solar cells with high efficiency [J].

Chung, In ;

Lee, Byunghong ;

He, Jiaqing ;

Chang, Robert P. H. ;

Kanatzidis, Mercouri G. .

NATURE, 2012, 485 (7399) :486-U94

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