Interface energetics in organo-metal halide perovskite-based photovoltaic cells

被引:616
作者
Schulz, Philip [1 ]
Edri, Eran [2 ]
Kirmayer, Saar [2 ]
Hodes, Gary [2 ]
Cahen, David [2 ]
Kahn, Antoine [1 ]
机构
[1] Princeton Univ, Dept Elect Engn, Princeton, NJ 08544 USA
[2] Weizmann Inst Sci, Dept Mat & Interfaces, IL-76100 Rehovot, Israel
基金
美国国家科学基金会;
关键词
LEAD BROMIDE PEROVSKITE; MESOSCOPIC SOLAR-CELL; LOW-COST; DEPOSITION; CRYSTALS;
D O I
10.1039/c4ee00168k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Direct and inverse photoemission spectroscopies are used to determine materials electronic structure and energy level alignment in hybrid organic-inorganic perovskite layers grown on TiO2. The results provide a quantitative basis for the analysis of perovskite-based solar cell performance and choice of an optimal hole-extraction layer.
引用
收藏
页码:1377 / 1381
页数:5
相关论文
共 21 条
[1]  
[Anonymous], NAT COMMUN
[2]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[3]   High performance hybrid solar cells sensitized by organolead halide perovskites [J].
Cai, Bing ;
Xing, Yedi ;
Yang, Zhou ;
Zhang, Wen-Hua ;
Qiu, Jieshan .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (05) :1480-1485
[4]   Chloride Inclusion and Hole Transport Material Doping to Improve Methyl Ammonium Lead Bromide Perovskite-Based High Open-Circuit Voltage Solar Cells [J].
Edri, Eran ;
Kirmayer, Saar ;
Kulbak, Michael ;
Hodes, Gary ;
Cahen, David .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (03) :429-433
[5]   High Open-Circuit Voltage Solar Cells Based on Organic-Inorganic Lead Bromide Perovskite [J].
Edri, Eran ;
Kirmayer, Saar ;
Cahen, David ;
Hodes, Gary .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2013, 4 (06) :897-902
[6]   Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells [J].
Eperon, Giles E. ;
Stranks, Samuel D. ;
Menelaou, Christopher ;
Johnston, Michael B. ;
Herz, Laura M. ;
Snaith, Henry J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (03) :982-988
[7]   Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells [J].
Eperon, Giles E. ;
Burlakov, Victor M. ;
Docampo, Pablo ;
Goriely, Alain ;
Snaith, Henry J. .
ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (01) :151-157
[8]   Electronic and Optical Properties of the Spiro-MeOTAD Hole Conductor in Its Neutral and Oxidized Forms: A DFT/TDDFT Investigation [J].
Fantacci, Simona ;
De Angelis, Filippo ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (46) :23126-23133
[9]   MAGNETOABSORPTION OF THE LOWEST EXCITON IN PEROVSKITE-TYPE COMPOUND (CH3NH3)PBI3 [J].
HIRASAWA, M ;
ISHIHARA, T ;
GOTO, T ;
UCHIDA, K ;
MIURA, N .
PHYSICA B, 1994, 201 :427-430
[10]   Perovskite cells roll forward [J].
Hodes, Gary ;
Cahen, David .
NATURE PHOTONICS, 2014, 8 (02) :87-88