Unusual Interlocking and Interpenetration Lead to Highly Porous and Robust Metal-Organic Frameworks

被引：115

作者：

Ma, Liqing ^{[1
]}

Lin, Wenbin ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 20期

基金：

美国国家科学基金会;

关键词：

gas storage; interlocking; interpenetration; metal-organic frameworks; porous materials; COORDINATION POLYMERS; ASYMMETRIC CATALYSIS; HYDROGEN STORAGE; ADSORPTION; REACTIVITY; H-2;

D O I：

10.1002/anie.200806227

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stop the breathing: As the organic bridging ligands become more elaborate and large, the resulting MOFs tend to experience significant framework distortion (i.e., breathing) upon solvent removal. Rigidification of MOFs that are built from elongated tetracarboxylate bridging ligands by unusual interlocking and interpenetration leads to highly porous and robust hybrid materials. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3637 / 3640

页数：4

共 33 条

[1] Stress-induced Chemical Detection Using Flexible Metal-Organic Frameworks
Allendorf, Mark D.
Houk, Ronald J. T.
Andruszkiewicz, Leanne
Talin, A. Alec
Pikarsky, Joel
Choudhury, Arnab
Gall, Kenneth A.
Hesketh, Peter J.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (44) : 14404 - +
[2] Blatov VA, 1999, RUSS J COORD CHEM+, V25, P453
[3] Surface interactions and quantum kinetic molecular sieving for H2 and D2 adsorption on a mixed metal-organic framework material
Chen, Banglin
Zhao, Xuebo
Putkham, Apipong
Hong, Kunlun
Lobkovsky, Emil B.
Hurtado, Eric J.
Fletcher, Ashleigh J.
Thomas, K. Mark
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (20) : 6411 - 6423
[4] A Luminescent Metal-Organic Framework with Lewis Basic Pyridyl Sites for the Sensing of Metal Ions
Chen, Banglin
Wang, Liangbo
Xiao, Yunqing
Fronczek, Frank R.
Xue, Ming
Cui, Yuanjing
Qian, Guodong
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (03) : 500 - 503
[5] A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation
Cho, So-Hye
Ma, Baoqing
Nguyen, SonBinh T.
Hupp, Joseph T.
Albrecht-Schmitt, Thomas E.
[J]. CHEMICAL COMMUNICATIONS, 2006, (24) : 2563 - 2565
[6] Crystal engineering of NLO materials based on metal-organic coordination networks
Evans, OR
Lin, WB
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) : 511 - 522
[7] Flexible porous metal-organic frameworks for a controlled drug delivery
Horcajada, Patricia
Serre, Christian
Maurin, Guillaume
Ramsahye, Naseem A.
Balas, Francisco
Vallet-Regi, Maria
Sebban, Muriel
Taulelle, Francis
Ferey, Gerard
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (21) : 6774 - 6780
[8] Highly interpenetrated metal-organic frameworks for hydrogen storage
Kesanli, B
Cui, Y
Smith, MR
Bittner, EW
Bockrath, BC
Lin, WB
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (01) : 72 - 75
[9] KESANLI B, 2005, ANGEW CHEM, V117, P74
[10] Metal-organic frameworks for asymmetric catalysis and chiral separations
Lin, Wenbin
[J]. MRS BULLETIN, 2007, 32 (07) : 544 - 548

← 1 2 3 4 →