Unusual Interlocking and Interpenetration Lead to Highly Porous and Robust Metal-Organic Frameworks

被引：115

作者：

Ma, Liqing ^{[1
]}

Lin, Wenbin ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 20期

基金：

美国国家科学基金会;

关键词：

gas storage; interlocking; interpenetration; metal-organic frameworks; porous materials; COORDINATION POLYMERS; ASYMMETRIC CATALYSIS; HYDROGEN STORAGE; ADSORPTION; REACTIVITY; H-2;

D O I：

10.1002/anie.200806227

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stop the breathing: As the organic bridging ligands become more elaborate and large, the resulting MOFs tend to experience significant framework distortion (i.e., breathing) upon solvent removal. Rigidification of MOFs that are built from elongated tetracarboxylate bridging ligands by unusual interlocking and interpenetration leads to highly porous and robust hybrid materials. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3637 / 3640

页数：4

共 33 条

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